Publications associées à Théorie du champ cristallin

The Cu-3d states in the high-T-c cuprates are often described as a single band of 3d(x2-y2) states, with the other four 3d states having about 2 to 3 eV higher energy due to the lower-than-octahedral crystal field at the copper sites. However, excitations ...

Amsterdam2023

Full Solution Process of a Near-Infrared Light-Emitting Electrochemical Cell Based on Novel Emissive Ruthenium Complexes of 1,10-Phenanthroline-Derived Ligands and a Eutectic Alloy as the Top Electrode

Mohammad Khaja Nazeeruddin

Near-infrared luminescent materials have recently received considerable attention for a large number of applications, including in solid-state lighting, as bioimaging agents, as photovoltaic cells, and in the telecommunication industry. By adding diverse e ...

AMER CHEMICAL SOC2023

Dynamic nuclear polarisation of 1H in Gd-doped In(OH)3

David Lyndon Emsley, Michael Allan Hope, Yuxuan Zhang, Amrit Venkatesh

Dynamic nuclear polarisation (DNP) of solids doped with high-spin metal ions, such as Gd3+, is a useful strategy to enhance the nuclear magnetic resonance (NMR) sensitivity for these samples. Spin diffusion can relay polarisation throughout a sample, which ...

ACADEMIC PRESS INC ELSEVIER SCIENCE2023

Charge fluctuations in the intermediate-valence ground state of SmCoIn5

Nicola Colonna, Vladimir N. Strocov, Neeraj Kumar

The microscopic mechanism of heavy band formation, relevant for unconventional superconductivity in CeCoIn5 and other Ce-based heavy fermion materials, depends strongly on the efficiency with which f electrons are delocalized from the rare earth sites and ...

NATURE PORTFOLIO2023

Manufacture and performance test result of a 95 kA-class Nb-Ti cable-in-conduit conductor for the low field winding-package of CFETR-TF coil

Pierluigi Bruzzone, Kamil Sedlák

The engineering design of the CFETR TF prototype coil and conductors has been completed. The wind-package (WP) of the coil is graded into three regions based on the magnetic field distribution for saving cost. High-Jc Nb3Sn strand, ITER-like Nb3Sn strand a ...

ELSEVIER2023

Dynamic Nuclear Polarization of Inorganic Halide Perovskites

David Lyndon Emsley, Michael Allan Hope, Dominik Józef Kubicki, Gabriele Stevanato, Aditya Mishra

The intrinsic low sensitivity of nuclear magnetic resonance (NMR) experiments limits their utility for structure determination of materials. Dynamic nuclear polarization (DNP) under magic angle spinning (MAS) has shown tremendous potential to overcome this ...

2023

Interfacial Inversion, Interference, and IR Absorption in Vibrational Sum Frequency Scattering Experiments

Sylvie Roke, Saranya Pullanchery Sankara Narayanan, Lei Zhang, Sergey Kulik

Molecular interfacial structure greatly determines thepropertiesof nano- and microscale systems. Vibrational sum frequency scattering(SFS) spectroscopy is a unique interface-selective tool to measurethe interfacial vibrational spectrum of sub-micron to mic ...

AMER CHEMICAL SOC2023

Improvements in Resolution of 1H NMR of Solids

David Lyndon Emsley, Bruno Simões de Almeida

Magic angle spinning (MAS) in 1H NMR has allowed progress from featureless spectra in static samples to linewidths of a few hundreds of Hertz for powdered solids at the fastest spinning rates available today (100-150 kHz). While this is a remarkable improv ...

SWISS CHEMICAL SOC2023

Quench experiments on sub-size HTS Cable-In-Conduit Conductors for fusion applications: Data analysis and model validation

Pierluigi Bruzzone, Kamil Sedlák, Boris Stepanov, Ortensia Dicuonzo

The recent experimental campaign, carried out in the upgraded SULTAN facility and supported by EUROfusion, investigated quench propagation in high field, sub-size HTS Cable-In-Conduit Conductors. The available experimental data consist of voltage, jacket a ...

ELSEVIER SCI LTD2023

Chattez avec Graph Search

Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.

AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.

Théorie du champ cristallin

Well-Defined Ti Surface Sites in Ziegler-Natta Pre-Catalysts from 47/49Ti Solid-State Nuclear Magnetic Resonance Spectroscopy

Can dd excitations mediate pairing?

Full Solution Process of a Near-Infrared Light-Emitting Electrochemical Cell Based on Novel Emissive Ruthenium Complexes of 1,10-Phenanthroline-Derived Ligands and a Eutectic Alloy as the Top Electrode

Dynamic nuclear polarisation of 1H in Gd-doped In(OH)3

Charge fluctuations in the intermediate-valence ground state of SmCoIn5

Manufacture and performance test result of a 95 kA-class Nb-Ti cable-in-conduit conductor for the low field winding-package of CFETR-TF coil

Dynamic Nuclear Polarization of Inorganic Halide Perovskites

Interfacial Inversion, Interference, and IR Absorption in Vibrational Sum Frequency Scattering Experiments

Improvements in Resolution of 1H NMR of Solids

Quench experiments on sub-size HTS Cable-In-Conduit Conductors for fusion applications: Data analysis and model validation

Graph Chatbot

Chattez avec Graph Search

Interfacial Inversion, Interference, and IR Absorption in Vibrational Sum Frequency Scattering Experiments

Manufacture and performance test result of a 95 kA-class Nb-Ti cable-in-conduit conductor for the low field winding-package of CFETR-TF coil

Dynamic Nuclear Polarization of Inorganic Halide Perovskites

Charge fluctuations in the intermediate-valence ground state of SmCoIn5

Dynamic nuclear polarisation of 1H in Gd-doped In(OH)3

Well-Defined Ti Surface Sites in Ziegler-Natta Pre-Catalysts from 47/49Ti Solid-State Nuclear Magnetic Resonance Spectroscopy

Quench experiments on sub-size HTS Cable-In-Conduit Conductors for fusion applications: Data analysis and model validation

Improvements in Resolution of 1H NMR of Solids