Concept

Ion cyclotron resonance

Résumé
Ion cyclotron resonance is a phenomenon related to the movement of ions in a magnetic field. It is used for accelerating ions in a cyclotron, and for measuring the masses of an ionized analyte in mass spectrometry, particularly with Fourier transform ion cyclotron resonance mass spectrometers. It can also be used to follow the kinetics of chemical reactions in a dilute gas mixture, provided these involve charged species. Definition of the resonant frequency An ion in a static and uniform magnetic field will move in a circle due to the Lorentz force. The angular frequency of this cyclotron motion for a given magnetic field strength B is given by :\omega = 2\pi f = \frac{zeB}{m}, where z is the number of positive or negative charges of the ion, e is the elementary charge and m is the mass of the ion. An electric excitation signal having a frequency f will therefore resonate with ions having a mass-to-charge ratio m/z given by :\frac{m}{z} = \frac{eB}{2\pi
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