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Concept
Single bond
Résumé
In chemistry, a single bond is a chemical bond between two atoms involving two valence electrons. That is, the atoms share one pair of electrons where the bond forms. Therefore, a single bond is a type of covalent bond. When shared, each of the two electrons involved is no longer in the sole possession of the orbital in which it originated. Rather, both of the two electrons spend time in either of the orbitals which overlap in the bonding process. As a Lewis structure, a single bond is denoted as AːA or A-A, for which A represents an element. In the first rendition, each dot represents a shared electron, and in the second rendition, the bar represents both of the electrons shared in the single bond.
A covalent bond can also be a double bond or a triple bond. A single bond is weaker than either a double bond or a triple bond. This difference in strength can be explained by examining the component bonds of which each of these types of covalent bonds consists (Moore, Stanitski, and Jurs 393).
Usually, a single bond is a sigma bond. An exception is the bond in diboron, which is a pi bond. In contrast, the double bond consists of one sigma bond and one pi bond, and a triple bond consists of one sigma bond and two pi bonds (Moore, Stanitski, and Jurs 396). The number of component bonds is what determines the strength disparity. It stands to reason that the single bond is the weakest of the three because it consists of only a sigma bond, and the double bond or triple bond consist not only of this type of component bond but also at least one additional bond.
The single bond has the capacity for rotation, a property not possessed by the double bond or the triple bond. The structure of pi bonds does not allow for rotation (at least not at 298 K), so the double bond and the triple bond which contain pi bonds are held due to this property. The sigma bond is not so restrictive, and the single bond is able to rotate using the sigma bond as the axis of rotation (Moore, Stanitski, and Jurs 396-397).
Another property comparison can be made in bond length.
Source officielle
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