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Concept
Janus particles
Résumé
Janus particles are special types of nanoparticles or microparticles whose surfaces have two or more distinct physical properties. This unique surface of Janus particles allows two different types of chemistry to occur on the same particle. The simplest case of a Janus particle is achieved by dividing the particle into two distinct parts, each of them either made of a different material, or bearing different functional groups. For example, a Janus particle may have one-half of its surface composed of hydrophilic groups and the other half hydrophobic groups, the particles might have two surfaces of different color, fluorescence, or magnetic properties. This gives these particles unique properties related to their asymmetric structure and/or functionalization.
The term "Janus Particle" was coined by author Leonard Wibberley in his 1962 novel The Mouse on the Moon as a science-fictional device for space travel.
The term was first used in a real-world scientific context by C. Casagrande et al. in 1988 to describe spherical glass particles with one of the hemispheres hydrophilic and the other hydrophobic. In that work, the amphiphilic beads were synthesized by protecting one hemisphere with varnish and chemically treating the other hemisphere with a silane reagent. This method resulted in a particle with equal hydrophilic and hydrophobic areas. In 1991, Pierre-Gilles de Gennes mentioned the term "Janus" particle in his Nobel lecture. Janus particles are named after the two faced Roman god Janus because these particles may be said to have "two faces" since they possess two distinct types of properties. de Gennes pushed for the advancement of Janus particles by pointing out these "Janus grains" have the unique property of densely self-assembling at liquid–liquid interfaces, while allowing material transport to occur through the gaps between the solid amphiphilic particles.
In 1976 Nick Sheridon of Xerox Corporation patented a Twisting Ball Panel Display, where he refers to a "plurality of particles which have an electrical anisotropy.
Source officielle
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