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Structured supported ionic liquid-phase (SSILP) catalysis is a new concept with the advantages of ionic liquids (ILs) used as solvents for homogeneous catalyst and the further benefits of structured heterogeneous catalysts. This is achieved by confining th ...
Two series of titania-based photocatalysts were prepared by the sputtering method, in pure Ar atmosphere at a pressure of 0.5 Pa using a vanadium target source in a direct dc mode with a discharge of 300 V. The time of deposition was varied between 1 and 1 ...
The activation of carbon-carbon σ bonds is a complementary method to access uncommon and difficult-to-prep. organometallic species. Herein, we describe the activation of tert-cyclobutanols through an enantioselective insertion of a chiral rhodium(I) compl ...
Parahydrogen-induced polarization was observed in the gas phase heterogeneous hydrogenation of propyne catalyzed by Pd-0 nanoparticles embedded in an ionic liquid phase supported on activated carbon fibers (Pd-0/SILP/ACF). The results were markedly differe ...
The tetradentate chelate ligand tris[(1-vinylimidazol-2-yl)methyl]amine (10) was synthesized in five steps from commercially available starting materials. Upon reaction with MCl2 (M = Zn, Cu, Ni, Co) in the presence of NH4PF6, the complexes [M(10)Cl]PF6 (M ...
New conditions have been found for the desulfitative Mizoroki-Heck arylation and trifluoromethylation of mono- and disubustituted olefins with arenesulfonyl and trifluoromethanesulfonyl chlorides. Thus (E)1,2-disubstituted alkenes with high stereoselectivi ...
The importance of catalysis in chemistry has not to be proved anymore. Be it homogeneous or heterogeneous catalysis, the constant progresses observed in that field proves its obvious interest. The asymmetric homogeneous catalysis is a method of choice to s ...
A ruthenium meso-tetra[4-(vinylbenzoxy)benzyl]porphyrin catalyst with four meso-polymerizable side chains was synthesized in three steps from commercially available starting materials. The polymerizable side chains allowed the incorporation of this complex ...
A combined d. functional theory/continuum electrostatics approach was used to est. the pKa values of metal-based compds. and their hydrolysis products. Specifically, the protonation states and abs. pKa values of [M(h6-arene)(X)(Y)(pta)]n+ (M = Ru or Os; ar ...
High-pressure NMR mechanistic investigations into the promoting role of dicarbonyldiiodoplatinum complex in the iridium-catalysed carbonylation of methanol to acetic acid are consistent with iodide abstraction from the [IrI3(CH3)(CO)2]– resting state speci ...
