Concept

Phosphorus trifluoride

Publications associées (19)

Developing the Catalytic Applications of 1,3,2-Diazaphospholenes

The development of new catalytic methods for organic synthesis is a critical endeavour in order to obviate the economic and ecological drawbacks of stoichiometric organic synthesis. While catalysis can offer significant advantages in terms of atom-economy, ...

EPFL2021

We report the influence of N-heterocyclic carbenes (NHCs) on the hydrolysis of a diphosphene TerP?PTer (1; Ter = 2,6-Mes(2)C(6)H(3); Mes = 2,4,6-Me3C6H2), a phosphorus-analogue of an alkene. The diphosphene 1 itself is completely inert towards water. Howev ...

ROYAL SOC CHEMISTRY2020

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OLED technology beyond small or expensive devices requires light-emitters, luminophores, based on earth-abundant elements. Understanding and experimental verification of charge transfer in luminophores are needed for this development. An organometallic mul ...

NATURE PUBLISHING GROUP2020

Given the great concern about phosphorus (P) resource depletion, it's promising to recover P from waste activated sludge (WAS) especially for agricultural application. To this end, it's necessary to understand the P speciation and fractionation within the ...

ELSEVIER SCIENCE SA2019

MOF-Derived Cobalt Phosphide/Carbon Nanocubes for Selective Hydrogenation of Nitroarenes to Anilines

Wendy Lee Queen, Emad Oveisi, Daniel Teav Sun, Shuliang Yang, Li Peng, Mehrdad Asgari, Olga Trukhina, Safak Bulut

Transition-metal phosphides have received tremendous attention during the past few years because they are earth-abundant, cost-effective, and show outstanding catalytic performance in several electrochemically driven conversions including hydrogen evolutio ...

2018

Synthesis of [Ru-II(eta(6)-p-cymene)(PPh3)(L)Cl]PF6 complexes with carbohydrate-derived phosphites, imidazole or indazole co-ligands

Christian Hartinger, Alexey Nazarov, Muhammad Hanif

Ru-II(arene) complexes of the general formula [Ru-II(eta(6)-p-cymene)(PPh3)(L)Cl]PF6 with L = P- or N-donor systems have been synthesized and characterized. Carbohydrate-derived phosphites, imidazole or indazole have been chosen as co-ligands and different ...

Elsevier2012

Proton and phosphorus magnetic resonance spectroscopy of a mouse model of Alzheimer's disease

Rolf Gruetter, Patrick Aebischer, Bernard Schneider, Cristina Ramona Cudalbu, Hongxia Lei, Sharon Janssens, Lili Sun-Reimer

The development of new diagnostic criteria for Alzheimer's disease (AD) requires new in vivo markers reflecting early pathological changes in the brain of patients. Magnetic resonance (MR) spectroscopy has been shown to provide useful information about the ...

Ios Press2012

Metal Phosphorus Complexes as Antitumor Agents

Paul Joseph Dyson, Alexey Nazarov

Phosphorus-based ligands are an extremely important class of ligand and they have found many applications, especially in homogeneous catalysis. In addition, a phosphine ligand is found in a gold drug used to treat rheumatoid arthritis. Since metal compound ...

Springer Netherlands2011

Primary productivity of continental and marine ecosystems is often limited or co-limited by phosphorus. Deposition of atmospheric aerosols provides the major external source of phosphorus to marine surface waters. However, only a fraction of deposited aero ...

2011

We have investigated the p- and n-type dopants in thin SGOI (20 nm) material obtained by Ge enrichment. The samples are doped with either BF2 or arsenic or phosphorus and then annealed with either a spike or a 15 s rapid thermal annealing in a temperature ...

2008

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