Publications associées à Acétate

Nanocrystalline ZnO Obtained by the Thermal Decomposition of [Zn(H2O)(O2C5H7)(2)] in 1-Butanol: Synthesis and Testing as a Sensing Material

The influence of conditions of heat treatment of a solution [Zn(H2O)(O2C5H7)(2)] in 1-butanol (temperature 125-185 degrees C, treatment times 2, 4, and 6 h) on dispersion and microstructure of the formed nanocrystalline and poorly aggregated zinc oxide, pr ...

MAIK NAUKA/INTERPERIODICA/SPRINGER2018

Long-life plastic optical fiber probes for scanning near-field optical microscope

Giovanni Dietler, Serguei Sekatski, Anton Smirnov, Ekaterina Rostova

Nowadays, sharpened glass fiber - made probes attached to a quartz tuning fork (TF) and exploiting the shear force - based feedback are by far the most popular in the field of SNOM. These probes are expensive, very fragile and their fabrication is difficul ...

SPIE-INT SOC OPTICAL ENGINEERING2018

Aqueous phase homogeneous formic acid disproportionation into methanol

Gabor Laurenczy, Katerina Stefania Sordakis

Herein we describe formic acid disproportionation into methanol with a homogeneous iridium catalyst. Methanol yields of up to 74% were obtained in D2O at 50 °C. Initial H2 pressures further enhanced methanol formation, resulting in a highly concentrated 9. ...

Royal Society of Chemistry2017

Economical Analysis of a Pressurized Fluid-Based Process Applied for Phytochemicals Recovery in a Sustainable Biorefinery Concept for Brazilian Ginseng Roots

François Maréchal

A growing number of technologies are being developed in order to produce different high added value products, such as phytochemicals, ethanol and other chemicals from biomass, representing an important trend that needs to be evaluated. The use of pressuriz ...

Aidic Servizi Srl2016

Direct noninvasive estimation of myocardial tricarboxylic acid cycle flux in vivo using hyperpolarized 13C magnetic resonance

Rolf Gruetter, Tian Cheng, Arnaud Comment, Hongxia Lei, Josefina Adriana Maria Bastiaansen

BACKGROUND: The heart relies on continuous energy production and imbalances herein impair cardiac function directly. The tricarboxylic acid (TCA) cycle is the primary means of energy generation in the healthy myocardium, but direct noninvasive quantificati ...

Elsevier2015

Synthesis and Reactivity of Mononuclear Iron Models of [Fe]-Hydrogenase that Contain an Acylmethylpyridinol Ligand

Xile Hu, Dafa Chen, Bowen Hu

[Fe]-hydrogenase has a single iron-containing active site that features an acylmethylpyridinol ligand. This unique ligand environment had yet to be reproduced in synthetic models; however the synthesis and reactivity of a new class of small molecule mimics ...

Wiley-V C H Verlag Gmbh2014

Direct, in situ determination of pH and solute concentrations in formic acid dehydrogenation and CO2 hydrogenation in pressurised aqueous solutions using 1H and 13C NMR spectroscopy

Paul Joseph Dyson, Gabor Laurenczy, Séverine Joëlle Moret

In water, spin–lattice relaxation times (T1) and calibration curves for chemical shifts have been determined for the 13C and the 1H (C) atoms in HCOOH, HCOONa, CO2, Na2CO3 and NaHCO3 by NMR spectroscopy. These data facilitate kinetic and mechanistic studie ...

Royal Soc Chemistry2013

Dual [proton]/[hole] mixed valence in a molecular metal: balancing chemical activity in the solid state by tapping into a molecular hole reservoir

László Forró, Bálint Náfrádi

We report on the synthesis, the layered triclinic P (1) over bar crystal structure, band structure and Fermi surface analysis and preliminary transport and ESR data of beta-(EDT-TTF-I-2)(2)((1+x)center dot+)HO2C-CH=CH-CO2--O2C-CH=CH-CO2-, a m ...

Royal Society of Chemistry2011

Control of morphology and nanostructure of copper and cobalt oxalates: Effect of complexing ions, polymeric additives and molecular weight

Heinrich Hofmann, Paul Bowen, Jacques Lemaître, Alke Fink, Nathalie Jongen

Precipitated oxalates are often nanostructured and can be used as precursors for nanostructured oxides for different applications. The modification of the particle shape and nanostructures of both copper and cobalt oxalates has been demonstrated using poly ...

2010

Cadmium adsorption to mixtures of soil components: Testing the component additivity approach

Daniel Scott Alessi

The ability to predict the distribution of metals in geologic systems requires a modeling approach that can describe the competition among adsorbing surfaces for the metal of interest. In this study, we test if a component additivity (CA) surface complexat ...

2010