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Publications associées (25)

Benzothiadiazole Aryl-amine Based Materials as Efficient Hole Carriers in Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Cristina Roldán Carmona, Manuel Alejandro Méndez Agudelo, Cristina Rodriguez Seco

Four hole transport materials (HTMs) based on a benzothiadiazole (BT) central core have been synthesized and successfully employed in triple-cation mixed-halide perovskite solar cells (PSCs), reaching 18.05% solar to energy conversion efficiency. The synth ...

AMER CHEMICAL SOC2020

Hole transporting materials for perovskite solar cells and a simple approach for determining the performance limiting factors

Mohammad Khaja Nazeeruddin, Iwan Zimmermann

The synthesis and characterization of three novel HTMs with different highest occupied molecular orbital (HOMO) energy levels and their performances in MAPbI(3)-based devices in comparison with Spiro-OMeTAD is reported. Without systematic optimization, the ...

2020

Heterobimetallic Ru(mu-dppm)Fe and homobimetallic Ru(mu-dppm)Ru complexes as potential anti-cancer agents

Paul Joseph Dyson, Lucinda Kate Batchelor

Two heterobimetallic mu-dppm bridged Fe,Ru complexes, [(eta(6)-Arene)RuCl2(mu-dppm)Fe(CO)I(eta(5)-C5H5)] (Ar - C6H6 (1) and p-cymene (2), dppm-1,1-bis(diphenylphosphino)methane) were obtained in a facile reaction between [Fe(eta(5)-C5H5)I(CO)(kappa(1)-dppm ...

2019

Electrochemical potential window of battery electrolytes: the HOMO-LUMO misconception

Hubert Girault, Pekka Eero Peljo

A widespread misconception in the lithium ion battery literature is the equality of the energy difference of HOMO and LUMO of the solvent with the electrochemical stability window. HOMO and LUMO are concepts derived from approximated electronic structure t ...

2018

Differentiating Siblings: The Case of Dopamine and Norepinephrine

Nako Nakatsuka

Monitoring dopamine and norepinephrine (or other structurally similar neurotransmitters) in the same brain region necessitates selective sensing. In this Viewpoint, we highlight electrochemical and optical strategies for advancing simultaneous real-time me ...

2017

2-homopiperazine-1-yl-4h-1,3-benzothiazine-4-one derivatives and process for the preparation of 2- (homo)piperazine 1,3-benzothiazine-4-one hydrochlorides

2-homopiperazine-1-yl-4H-l, 3 -bensothiazine-4-one derivatives of formula (I) are provided. They are useful in the treatment of bacterial infections, in particular tuberculosis, buruli ulcer and leprosy. A process for the preparation of 2- (homo)piperazine ...

2016

Molecular Engineering of Iridium Blue Emitters Using Aryl N-Heterocyclic Carbene Ligands

Mohammad Khaja Nazeeruddin, Iwan Zimmermann, Giulia Grancini, Aron Joel Huckaba, Sadig Aghazada

The synthesis of a new series of neutral bis[2-(2,4-difluorophen-2-yl)pyridine][1-(2-aryl)-3-methylimidazol-2-ylidene]iridium(III) complexes is reported. Each complex has been characterized by NMR spectroscopy, UV/Vis spectrophotometry, and cyclic voltamme ...

Wiley-Blackwell2016

Strategy to Boost the Efficiency of Mixed-Ion Perovskite Solar Cells: Changing Geometry of the Hole Transporting Material

Nikolaos Vlachopoulos, Ulf Anders Hagfeldt, Jiahuan Zhang

The hole transporting material (HTM) is an essential component in perovskite solar cells (PSCs) for efficient extraction and collection of the photoinduced charges. Triphenylamine- and carbazole-based derivatives have extensively been explored as alternati ...

Amer Chemical Soc2016

Structured light enables biomimetic swimming and versatile locomotion of photoresponsive soft microrobots

Peer Fischer, Tian Qiu, Hao Zeng

Microorganisms move in challenging environments by periodic changes in body shape. In contrast, current artificial microrobots cannot actively deform, exhibiting at best passive bending under external fields. Here, by taking advantage of the wireless, scal ...

Nature Publishing Group2016

Two-Dimensional Metal-Organic Networks as a New Class of Electrocatalysts

Benjamin Wurster

This thesis deals with the electrocatalytic properties of two-dimensional metal organic coordination networks (2D-MOCNs) self-assembled on electrode surfaces and catalytic activity of 2D-MOCNs is demonstrated for the first time. The low-coordinated metal c ...

EPFL2015

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