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Enantioselective Rh-promoted activation and 1,4-positional swap of unactivated tetraorganosilanes, e.g., 1-ethyl-3-methyl-3-(2-(trimethylsilyl)phenyl)cyclobutanol (I) to give (1S,3S)-1-ethyl-3-methyl-3((trimethylsilyl)methyl)indanol (II). E.g., reaction of ...
We study the phase behaviour of symmetric binary mixtures of hard core Yukawa (HCY) particles via thermodynamic perturbation theory (TPT). We show that all the topologies of phase diagram reported for the symmetric binary mixtures are correctly reproduced ...
A simple one-step heat-treatment of peroxotitanate complex aqueous solution at around 100 degrees C was resulted in the formation of ellipsoidal anatase TiO2 nanoparticles having a high aspect ratio with no branches. The length of these ellipsoidal TiO2 fa ...
The Diels-Alder reaction has been examd. in room temp. ionic liqs. with high molar concns. of Lewis acids under various conditions. A molar ratio of 10% catalyst gave a large increase in the selectivity and the yield of the reaction. The effect of catalyst ...
With the progress of miniaturization, in many modern applications the characteristic dimensions of the physical volume occupied by particle-reinforced composites are getting comparable with the reinforcement size and many of those composite materials under ...
In most models of perceptual learning, the amount of improvement of performance does not depend on the regime of stimulus presentations, but only on the sheer number of trials. Here, we kept the number of stimulus presentations constant while varying the n ...
Al/SiC composites with volume fractions of SiC between 0.55 and 0.71 were made from identical tapped and vibrated powder preforms by squeeze casting (SC) and by two different setups for gas pressure infiltration (GPI), one that allows short (1-2 min) liqui ...
We report on a series of soil erosion experiments performed on the 2-m x 6-m EPFL erosion flume. Total sediment concentrations and the concentrations of seven size fractions (1000 mm) were measured during 1 ...
We present a particle-sorting device based on the opposition of dielectrophoretic forces. The forces are generated by an array of electrode chambers located in both sidewalls of a main flow channel. Particles with different dielectric response perceive dif ...
The temperature-dependent thermo-physical and mechanical properties of a pultruded E-glass fiber-reinforced polyester (GFRP) composite are investigated in this paper. Fitting of theoretical models of the material properties to results of TGA, DSC, hot disk ...