Publications associées (262)

Enabling simultaneous reprocessability and fire protection via incorporation of phosphine oxide monomer in epoxy vitrimer

Véronique Michaud, Valentin Rougier

The conception of epoxy thermosets with both reprocessability and flame retardancy delineates a new horizon in polymer science, offering a material solution that is not only superior in fire safety but is also environment friendly. Herein, a flame-retardan ...
Journal Mater Sci Technol2024

Biobased Composites from Eugenol- and Coumarin-Derived Methacrylic Latex and Hemp Nanocellulose: Cross-Linking via [2+2] Photocycloaddition and Barrier Properties

Yves Leterrier, Sara Dalle Vacche

A novel-biobased latex was synthesized by redox-initiated emulsion copolymerization of ethoxy dihydroeugenyl methacrylate with 5 wt % of a photosensitive methacrylate containing a coumarin group. A stable copolymer latex having 16 wt % solids content and a ...
Amer Chemical Soc2024

Influence of Si3N4 fillers and pyrolysis profile on the microstructure of additively manufactured silicon carbonitride ceramics derived from polyvinylsilazane

In this work, various methods were used to improve the printability of a photocurable polyvinylsilazane resin filled with silicon nitride particles for digital light processing. The developed resin was used as a preceramic polymer for polymer-to-ceramic co ...
Taylor & Francis Ltd2024

Self-catalysed frontal polymerisation enables fast and low-energy processing of fibre reinforced polymer composites

Véronique Michaud, Jacobus Gerardus Rudolph Staal, Baris Çaglar

Frontal polymerisation has the potential to bring unprecedented reductions in energy demand and process time to produce fibre reinforced polymer composites. Production of epoxy-based fibre reinforced polymer parts with high fibre volume content, commonly e ...
2024

Multilayer diffusion-barrier composites based on microfibrillated cellulose from wood, bacterial and algae sources

Aigoul Schreier

This work is driven by the effort towards increased environmental sustainability and aims to develop a new food packaging material based on renewable materials, and more specifically cellulose as the most abundant biomass resource on Earth. Focus was on mi ...
EPFL2024

Multimaterial Volumetric Printing of Silica-Based Glasses

Christophe Moser, Paul Delrot, Jorge Andres Madrid Wolff, Damien Claude-Marie Loterie, Antoine Vincent Boniface, Roberto Arturo Emma

Silicate glasses have played a major role as structural and functional materials in human civilization since ancient Egypt. Despite their widespread use and importance in modern society, silica glasses with complex geometries are only fabricated in automat ...
Hoboken2024

Large-Scale Hollow-Core 3D Printing: Variable Cross-Section and Printing Features for Lightweight Plastic Elements

Hollow-core 3D printing (HC3DP) proposes a new method for the production of lightweight, material-efficient thermoplastic 3D printed elements. This new fabrication approach promises material savings of 50-80%, while increasing the extrusion rate significan ...
Mary Ann Liebert, Inc2024

Recyclable flame retardant phosphonated epoxy based thermosets enabled via a reactive approach

Véronique Michaud, Valentin Rougier

The development of reusable fire-safe polymers with a prolonged lifetime heralds the switch for a transition towards circular economy. In this framework, we report a novel phosphonated thermoset which is composed of networked phosphonate esters containing ...
ELSEVIER SCIENCE SA2023

CRACK SHIELDING MECHANISMS OF INTERLAYERED EPOXY MATERIALS UNDER QUASI-STATIC AND FATIGUE LOADING

Anastasios Vassilopoulos, Dharun Vadugappatty Srinivasan

This research explores the capability of PEI and PVDF thermoplastic interlayers to arrest cracks in epoxy materials modified with short-glass fibers and core-shell rubber particles. It also investigates the effect of interlayer position, the number of inte ...
Queen's University Belfast2023

Incorporation of Lignin in Bio-Based Resins for Potential Application in Fiber-Polymer Composites

Mário Alexandre De Jesus Garrido, Mateus De Assunção Hofmann

Bio-based resins, obtained from renewable raw materials, are a more sustainable alternative to oil-based resins for fiber-reinforced polymer (FRP) composites. The incorporation of lignin in those resins has the potential to enhance their performance. This ...
MDPI2023

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