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Partial oxidn. of toluene on V/Ti oxide catalysts is a reaction of industrial interest. In spite of the detailed study of the nature of surface vanadia species, there is an evident lack of the information concerning their reactivity. The present work demon ...
The influence of potassium on the formation of surface vanadia species on V/Ti oxide catalysts contg. from 0.2 to 5 monolayers of vanadia (K/V at. surface ratio ?1) has been investigated by temp. programmed redn. in hydrogen and by FT-Raman spectroscopy un ...
The prepn. of large arrays of iron oxide (α-Fe2O3) and iron oxyhydroxide (β-FeOOH) as monodisperse perpendicular single-cryst. nanorods grown directly onto a polycryst. (or single-cryst.) substrate from an aq. soln. of ferric salts, without any template, m ...
The lifetimes of non-fixed holograms in LiNbO3 crystals with different dopants, doping levels and oxidation states have been measured in the temperature range from 30 to 180degrees C. Two dark decay mechanisms have been identified: proton compensation and ...
Polyethylene block-copolymer films containing negative anhydride groups were used to immobilize TiO2, Fe2O3, and Fe3+ photocatalysts. The kinetics of the mineralization of azo-dye Orange II and chlorophenols on copolymer−TiO2, copolymer−Fe2O3, and copolyme ...
Aquifer samples from the precipitation zone of an in situ iron and manganese removal plant that was operated for 10 years were analyzed for iron and manganese minerals. Measurements were performed by various chemical extraction techniques (5 M HCl, 0.0081 ...
Small addition of potassium to V/Ti-oxide catalyst (K:V=0.19), consisting of 3.7 monolayer VOx, increased activity and selectivity in partial oxidation of toluene. In order to elucidate the nature of vanadia species formed on the surface of V/Ti-oxide upon ...
The partial oxidn. of toluene over V2O5/TiO2 catalysts is a reaction of industrial interest. In spite of the detailed study of the nature of surface vanadia species, there is an evident lack of the information concerning their reactivity. The present work ...
We have performed thermal measurements and electrothermal simulations (finite element modelling) with the aim of optimizing the power consumption and the temperature distribution of micro-hotplates for gas-sensing applications. A silicon island was added u ...
V substituted phosphomolybdic acids could hydroxylate benzene with nearly 100% selectivity at appreciable conversion levels in the presence of oxidizing agents like H2O2 and AcOOH. There appears to be a correlation, for the liq. phase, between phenol yield ...