Alternative natural materials | EPFL Graph Search

Alternative natural materials are natural materials like rock or adobe that are not as commonly in use as materials such as wood or iron. Alternative natural materials have many practical uses in areas such as sustainable architecture and engineering. The main purpose of using such materials is to minimize the negative effects that our built environment can have on the planet while increasing the efficiency and adaptability of the structures. History Alternative natural materials have existed for quite some time but often in very basic forms or only as ingredients to a particular material in the past. For example, earth used as a building material for walls of houses has existed for thousands of years. Much more recently, in the 1920s, the United States government promoted rammed earth as a fireproof construction method for building farmhouses. Another more common example is adobe. Adobe homes are prominent in the southwestern U.S. and several Spanish-speaking countries.

Carbonation of low carbon binders

Wioletta Soja

To reduce the impact of the embodied energy and of the carbon dioxide emissions of concrete, the use of supplementary cementitious materials (SCMs) in the cement industry has become a common practice. However, the practical experience on such cements is limited due to the lower strength at early ages and the concern about long term performance, especially potentially higher carbonation rates due to a lower capacity to bind CO2. To increase the protection of the steel in the concrete where carbonation might be a risk, the full understanding of the microstructure changes due to carbonation is necessary. The main goal of this thesis is to characterise and to quantify the correlation between transport properties and modification of the microstructure in the carbonated concrete. We propose a new approach to obtain a representative specimen of âfully carbonatedâ material in relatively short time. The innovative idea of using a thin cement paste sample allowed the characterization of the gas diffusion properties in naturally carbonated cement paste. This, together with the measured changes in phase assemblage and pore structure, can be used to better understand the reactive transport model. The adaptation to natural exposure conditions ensures obtaining representative results. Investigating the governing parameters of carbonation and emphasizing the influence of the non-carbonated reference advanced the understanding of the carbonation mechanism, especially in the low carbon binders. This study sheds a new light at the problem of overestimating the effect of carbonation on the microstructure of the cementitious material. In particular, it shows the importance of subtracting the effect of the drying taking place during carbonation, to diminish the risk of attributing the changes in porosity only to carbonation. The monitoring of the changes in the phase assemblage and the assessment of the carbonation coefficient during exposure to carbonation showed a promising performance of the new ternary blend with 50 % clinker replacement by burnt oil shale, slag, and limestone. The obtained results on characterisation of the carbonating binders can be used to improve carbonation models, that are essential to predict the resistance of new types of cements. That could help to assess the balance between the benefits of using alternative materials, and the potential danger of low resistance against carbonation. The profit will be to make cement and concrete even more sustainable and a more environmentally friendly construction material.

EPFL2019

DEVELOPMENTS ON SRF COATINGS AT CERN

Barbora Bártová, Alban Sublet

The thin films techniques applied to Superconducting RF (SRF) have a long history at CERN. A large panel of cavities has been coated from LEP, to LHC. For the current and future projects (HIE-ISOLDE, HL-LHC, FCC) there is a need offurther higher RF-performances with focus on minimizing residual resistance Rres and maximizing quality factor Q0 of the cavities. This paper will present CERN’s developments on thin films to achieve these goals through the following main axes of research: The first one concerns the application of different coating techniques for Nb (DC-bias diode sputtering, magnetron sputtering and HiPIMS). Another approach is the investigation of alternative materials like Nb3Sn. These lines of development will be supported by a material science approach to characterize and evaluate the layer properties by means of FIB-SEM, TEM, XPS, XRD, etc. In addition a numerical tool for plasma simulation will be exploited to develop adapted coating systems and optimize the coating process, from plasma generation to thin film growth.

2015

Carbonation of low carbon binders

Wioletta Soja

EPFL2019