Publications associées à Endofullerène

Direct Observation of the Phase Transition in C60 Fullerene

In the third study, the order-disorder phase transition of single-crystal C60 is studied using time-resolved electron microscopy. Solid C60 undergoes a first-order phase transition upon heating to 260 K. This is a structural transition from the low-tempera ...

EPFL Infoscience2023

Synthetic Receptors with Micromolar Affinity for Chloride in Water

Kay Severin, Farzaneh Fadaei Tirani, Damien Wen Chen, Cesare Berton, Sylvain Alexandre Marie Sudan

A water-soluble coordination cage was obtained by reaction of Pd(NO3)2 with a 1,3-di(pyridin-3-yl)benzene ligand featuring a short PEG chain. The cavity of the metal-organic cage contains one nitrate anion, which is readily replaced by chloride. The appare ...

Wiley-VCH Verlag GmbH2023

Site-selective Synthesis of -[70]PCBM-like Fullerenes: Efficient Application in Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jiyoun Seo, Seckin Akin

We report on the site-selective synthesis of PCBM-like [70]fullerene site-isomers, where the elusive -site-isomers are, for the first time, the major product in a (cyclo)addition chemical reaction involving [70]fullerene. The reaction involves an straightf ...

WILEY-V C H VERLAG GMBH2019

Koopmans Meets Bethe-Salpeter: Excitonic Optical Spectra without GW

Nicola Marzari, Nicola Colonna, Paolo Umari

The Bethe Salpeter equation (BSE) can be applied to compute from first-principles optical spectra that include the effects of screened electron hole interactions. As input, BSE calculations require single-particle states, quasiparticle energy levels, and t ...

AMER CHEMICAL SOC2019

Performance of Carbon Nano-Scale Allotropes in Detecting Midazolam and Paracetamol in Undiluted Human Serum

Giovanni De Micheli, Nima Aliakbarinodehi, Sandro Carrara, Francesca Stradolini, Irene Taurino, Ioulia Tzouvadaki, Sattar Akbari Nakhjavani

Nano-materials are highly exploited to enhance sensing performance of electrochemical electrodes by increasing the Electro-Active Surface Area (EASA). In this work, an analytical calculation of the deposited EASA is presented and experimentally validated b ...

2018

Lattice Energy as Emerging General Parameter Describing Ionic Organic Semiconducting Materials Properties

Donatas Gesevicius

Cyanine dyes represent a class of ionic functional materials used by a broad heterogeneous science community contain-ing biologists, chemists, physicists and materials scientists. Their diverse application opportunities are ranging from fluorescence marker ...

EPFL2018

Stable 2.1 μm near 100% polarized Ho-doped all-fiber laser based on a polarizer-free cavity scheme

Camille Sophie Brès, Davide Grassani, Jianqi Hu, Svyatoslav Kharitonov, Sida Xing

A highly polarized Ho-doped truly all-fibre laser was demonstrated without in-cavity polarizer. Utilizing PM-FBG and loop mirror, maximum 0.5W output power with 30% slope efficiency, 70dB ASE suppression and 99.997% degree of polarization was recorded at 2 ...

2017

Self-Assembled Nanomicelles as MRI Blood-Pool Contrast Agent

Lothar Helm, Anne-Sophie Chauvin, Vassily Vorobiev

Gadolinium‐loaded nanomicelles show promise as future magnetic resonance imaging (MRI) contrast agents (CAs). Their increased size and high gadolinium (Gd) loading gives them an edge in proton relaxivity over smaller molecular Gd‐complexes. Their size and ...

2017

A Close Look at Charge Generation in Polymer:Fullerene Blends with Microstructure Control

Jacques-Edouard Moser, Natalie Renuka Banerji, Mariateresa Scarongella, Jelissa Risse, Natalie Stingelin

We reveal some of the key mechanisms during charge generation in polymer:fullerene blends exploiting our well-defined understanding of the microstructures obtained in pBTTT:PCBM systems via processing with fatty acid methyl ester additives. Based on ultraf ...

Amer Chemical Soc2015

First-principles investigation of organic photovoltaic materials C-60, C-70, [C-60]PCBM, and bis-[C-60]PCBM using a many-body G(0)W(0)-Lanczos approach

Nicola Marzari, Paolo Umari

We present a first-principles investigation of the excited-state properties of electron acceptors in organic photovoltaics including C-60, C-70, [6,6]-phenyl-C-61-butyric-acid-methyl-ester ([C-60] PCBM), and bis-[C-60] PCBM usingmany-body perturbation theo ...

Amer Physical Soc2015