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In this article we highlight some of the recent developments in the aqueous-phase hydrogenation of alkenes and arenes. The traditional types of water-soluble catalysts applied in aqueous media are outlined together with recent trends towards the developmen ...
We demonstrate that the combination of x-ray irradiation and capping by polyethylene glycol (PEG) produces excellent flexibility in controlling the structure of Au-Pd nanoparticles while preserving their catalytic performance. We specifically adopted two d ...
Iron(III) bisoxazolinylphenylamido (bopa) pincer complexes are efficient precatalysts for the cross-coupling of nonactivated primary and secondary alkyl halides with phenyl Grignard reagents. The reactions proceed at room temperature in moderate to excelle ...
A highly enantioselective, chiral, Lewis acid calcium–bis(phosphate) complex, Ca[3a]n, which catalyzes the electrophilic amination of enamides with azodicarboxylate derivatives 2 to provide versatile chiral 1,2-hydrazinoimines 4 is disclosed. The reaction ...
The cydopentadienyl (Cp) group is a ligand of great importance for many transition-metal complexes used in catalysis. Cationic CpRuII complexes with three free coordination sites are highly versatile catalysts for many atom-economic transformations. We rep ...
The development of selective Pd-based catalyst for semi-hydrogenation of dehydroisophytol (DIP), a C20-alkynol, is reported. A series of unsupported mono- (Pd) and bimetallic (Pd-M) nanoparticles (NPs) with Pd/M molar ratios of 1.5 - 5.0 (M = Ag or Cu) wer ...
The present study was initiated with the aim to assess the in vivo electrochemical corrosion behaviour of CoCrMo biomedical alloys in human synovial fluids in an attempt to identify possible patient or pathology specific effects. For this, electrochemical ...
We demonstrate that the combination of x-ray irradiation and capping by polyethylene glycol (PEG) produces excellent flexibility in controlling the structure of Au–Pd nanoparticles while preserving their catalytic performance. We specifically adopted two d ...
Functional nanostructured carbon materials, including two-dimensionally extended nanosheets, offer
intriguing perspectives for applications in emerging technologies such as hydrogen storage, lithium
storage, transition metal free catalysis, or solar abso ...
Catalyst design is of major importance for fine chemicals industry due to
complexity of the synthesis and high product quality requirements. Moreover, the
catalyst formulation has to comply with the standards of health, safety and
environmental regulati ...