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At the beginning of this article an in-depth comparison of electrophilic and nucleophilic aromatic and heterocyclic substitution processes examines their scopes of applicability in a new light. In the subsequent parts, recent progress in the area of halide ...
Gold nanoparticles (NPs) stabilized by carboxylate modified polyvinylpyrrolidone have been prepared and fully characterized. The gold NPs efficiently catalyze the aerobic oxidation of benzyl alcohol in water at ambient temperature and are easily separated ...
An important microstructural aspect of the early hydration of Portland cement (K) is the formation of a shell of hydration products around cement grains. There is, at present, limited information on the mechanism of formation of the shell and of the chemis ...
Lack of improved drinking water sources contributes a lot to many waterborne diseases caused by pathogens which include viruses, protozoa, bacteria or worms. It is essential to develop and promote treatment methods in order to provide pathogen-free safe dr ...
Hydrolytic: cleavage of the oligopeptides Ace-Ala-Lys-Tyr-Gly similar to Gly-Met-Ala-Ala-Arg-Ala and Ace-Lys-Gly-Gly-Ala-Gly similar to Pro-Met-Ala-Ala-Arg-Gly by Pd(H2O)(4) was theoretically investigated by using molecular dynamics simulations and q ...
The characterization of Fe/ZSM5 zeolite materials, the nature of Fe-sites active in N2O direct decomposition, as well as the rate limiting step are still a matter of debate. The mechanism of N2O decomposition on the binuclear oxo-hydroxo bridged extraframe ...
Reductive dissolution of redox-sensitive minerals such as manganese (Mn) oxides in natural sediments is an important mechanism for trace element mobilization into groundwater. A gel probe sampler has been constructed to study in situ reductive dissolution ...
We study chemical bath deposition method for synthesizing large variety constructions of ZnO nanostructures. By varying reaction kinetics we control the shape, size and morphology to yield flower-like, rolling-pin-like, viscous-fingers-like and antenna-lik ...
Minimal state representations are parsimonious models having no redundant states. For homogeneous reaction systems with S species, R independent reactions, p independent inlet streams and one outlet stream, a nonlinear transformation of the numbers of mole ...
This paper explores the degradation of a model pollutant, bisphenol A, by an advanced oxidation process that combines sonolysis, Fe2+, and TiO2 in a photoassisted process. Experiments were done under saturated oxygen conditions. The effect of different Fe2 ...