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Fabrication conditions to obtain dense electrolyte double layers on a porous micro-tubular cathode substrate were investigated. Porous tubes of a nickelate material, Nd1.95NiO4 + δ, were fabricated by cold-isostatic pressing (CIP) and sintering. Thin films ...
The aim of this study was to evaluate the rate and mechanism of conversion of two water-soluble prodrugs of cyclosporine A (CsA) intended for topical delivery to the eye. The new molecules were designed according to the double prodrug concept: a solubilizi ...
We present a theoretical and experimental analysis of the dam break of a viscoplastic fluid in a horizontal channel. A shallow, slow fluid model based on the Herschel-Bulkley constitutive law allows one to characterize the early and late stages of the flow ...
The potential of chlorine dioxide (ClO2) for the oxidation of pharmaceuticals during water treatment was assessed by determining second-order rate constants for the reaction with selected environmentally relevant pharmaceuticals. Out of 9 pharmaceuticals o ...
The goal of this thesis was to open a new route to the synthesis of conjugated trienes using a new SO2-based C-C bond forming reactions developed in Lausanne. In addition, the potential of SO2 for applications in synthetic organic chemistry has been exploi ...
The water-soluble Ru(II)-phosphine complex, [{RuCl2(mTPPMS)(2)}(2)] was found a suitable catalyst for the hydrogenation of NaHCO3 to NaHCO2 in aqueous solution under mild conditions with catalyst turnover frequencies (TOFs) in the range of 35-50 h(-1) at 5 ...
The ability of ferrate (Fe(Vl)) to oxidize phenolic endocrine-disrupting chemicals (EDCs) and phenols during water treatment was examined by determining the apparent second-order rate constants (k(app)) for the reaction of Fe(VI) with selected environmenta ...
This study investigated the oxidation of the oral contraceptive 17alpha-ethinylestradiol (EE2) during ozonation. First, the effect of ozone (O-3) on the estrogenic activity of aqueous solutions of EE2 was studied using a yeast estrogen screen (YES). It cou ...
Lymphatic vessels exist in nearly all tissues, yet, despite their omnipresence, there remains a large knowledge gap between the described fundamental roles of lymphatic capillaries and our understanding of their functional biology, adaptive ability, and pa ...
We present a comprehensive study of multiple-scattering effects in wide-field optical coherence tomography (OCT) realized with spatially coherent illumination. Imaging a sample made of a cleaved mirror embedded in an aqueous suspension of microspheres reve ...
