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Several hydrophobic long-chain quaternary ammonium and phosphonium ionic liquids (ILs) with functionalized aromatic anions were prepared following a metathesis route using tricaprylmethylammonium chloride (Aliquat 336) and trihexyl(tetradecyl) phosphonium ...
Heterogeneous nucleation is governed by the interplay of interfacial energies between a substrate, a solid and a liquid. Although the intensity of these energies can strongly change with the orientation of the nucleus for anisotropic media, this parameter ...
Total dissolved and labile concentrations of Cd(II), Cu(II), Ni(II) and Pb(II) were determined at six locations of the Bourgas Gulf of the Bulgarian Black Sea coast. Solid phase extraction procedure based on monodisperse, submicrometer silica spheres modif ...
Easy immobilisation of carbon nanofillers in a solid state device featuring mesopores filled with ionic liquid (IL) is presented. Such a route allows a good dispersion of carbon nanotubes (CNTs) and carbon fibers in N-methyl-N-propylpyrrolidinium bis(trifl ...
The achievement of high ionic conductivity in new "polymeric ionic liquids" (PILs) is of great interest as it refers to the solid state electrolytes and their applications in electrochemistry. Four ionic monomers, including two new ones, namely N-[(2-metha ...
In biomass gasification, particles such as condensed alkali salts pose a threat on equipment. Due to high loads of condensable tars in the gases, sampling of these particles to liquids and subsequent analysis of the liquid is frequently the method of choic ...
The complexation reactions between strontium (Sr2+) and octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) were studied at the aqueous vertical bar 1,2-dichloroethane (w vertical bar DCE) and aqueous vertical bar room-temperature ionic liqui ...
The achievement of high ionic conductivity in single-ion conducting polymer electrolytes is one of the important aims for various electrochemical devices including modern lithium batteries. One way to enhance the ionic conductivity in polyelectrolyte syste ...
Uranium building blocks: Two new uranium cluster topologies are obtained from the stoichiometric hydrolysis of low-valent uranium in non-aqueous media (see picture). The organic base TMEDA directs the self-assembly process towards the formation of a nanosi ...
