Publications associées à Prelog strain

Oxidative rearrangement of 1,1-disubstituted alkenes to ketones

The Wacker process, which is widely used to convert monosubstituted alkenes into the corresponding methyl ketones, is thought to proceed through a PdII/Pd0 catalytic cycle involving a b-hydride elimination step. This mechanistic scenario is inapplicable to ...

American Association for the Advancement of Science2023

Energy dissipation in fiber-polymer composites adhesive joints under cyclic loading

Ghazaleh Eslami

Sustainable development has emerged as a paramount consideration in various fields of industry, including construction, to preserve the environment and its finite resources. Lightweight structures, such as fiber-polymer composite structures, address both s ...

EPFL2023

Cycloalkane Oxidation Catalyzed by Copper-based Catalysts with H2O2 under Mild Conditions

Nukorn Plainpan, Jantira Chimlert

Copper-catalyzed cycloalkane oxidation using H2O2 as an oxidant was investigated under mild conditions. The copper catalysts studied in this work ranged from commercially-available copper(II) salts to copper(II) complexes containing polypyridyl ligands. Va ...

WILEY-V C H VERLAG GMBH2023

Activation of aminocyclopropanes via radical intermediates

Jérôme Waser, Mingming Wang

Aminocyclopropanes are versatile building blocks for accessing high value-added nitrogen-containing products. To control ring-opening promoted by ring strain, the Lewis acid activation of donor-acceptor substituted systems is now well established. Over the ...

Royal Society of Chemistry2022

Deformation twinning mechanism in magnesium at the microscale: strain rate, temperature and orientation effects

Nicolò Maria Della Ventura

The project aims to validate some recent theoretical developments on the deformation twinning nucleation mechanism in HCP metals through small-scale mechanic experiments. To this end, a systematic investigation of the mechanical response of pure magnesium ...

EPFL2022

Scaling Description of Creep Flow in Amorphous Solids

Matthieu Wyart, Thomas Willem Jan de Geus, Wencheng Ji, Marko Popovic

Amorphous solids such as coffee foam, toothpaste, or mayonnaise display a transient creep flow when a stress E is suddenly imposed. The associated strain rate is commonly found to decay in time as gamma_ -t-nu, followed either by arrest or by a sudden flui ...

AMER PHYSICAL SOC2022

Umbrella Meshes: Elastic Mechanisms for Freeform Shape Deployment

Mark Pauly, Florin Isvoranu, Uday Kusupati, Yingying Ren, Tian Chen, Davide Pellis

We present a computational inverse design framework for a new class of volumetric deployable structures that have compact rest states and deploy into bending-active 3D target surfaces. Umbrella meshes consist of elastic beams, rigid plates, and hinge joint ...

2022

Mechanical performance and upscaling of bio-improved soils

Ray Harran

Ecological awareness, pressing climate considerations and rising need for soil stabilization push forward the quest for alternative solutions in geotechnical engineering such as Microbially Induced Carbonate Precipitation (MICP). Precipitated crystals serv ...

EPFL2022

Order parameters for antiferromagnetic structures: A first-principles study of iridium manganese

Anirudh Raju Natarajan

We use density-functional theory to study the ordered states of iridium manganese, demonstrating a simple but powerful method for describing magnetic structures and the transitions among them. As an illustrative example, the coupling of magnetism and cryst ...

AMER PHYSICAL SOC2022

A probabilistic deformation-based seismic hazard model for Iran

Alireza Khodaverdian

Probabilistic seismic hazard analysis, as the most prevalent approach to evaluate earthquake hazard, is commonly based on earthquake catalogs. Although previous studies show that the recurrence time of large-magnitude (M-w > 7.0) events in Iran is more tha ...

2022