Concept

Thermodynamic state

Publications associées (382)

How uncertainty in kinetic parameters affects metabolic control analysis of optimally grown E.coli

Vassily Hatzimanikatis, Ljubisa Miskovic, Meriç Ataman, Georgios Fengos, Tuure Eelis Hameri

Large-scale kinetic models of metabolism are essential for understanding and predicting the behavior of cellular systems when subject to perturbations. Despite the advances in experimental measurement technologies, the numerous parameters that are require ...

2016

A universal chemical potential for sulfur vapours

Davide Tiana

The unusual chemistry of sulfur is illustrated by the tendency for catenation. Sulfur forms a range of open and closed S-n species in the gas phase, which has led to speculation on the composition of sulfur vapours as a function of temperature and pressure ...

Royal Soc Chemistry2016

Thermodynamic modeling of gas-liquid-water partitioning and fluid properties for Macondo reservoir fluid at deep-water conditions

Jeremy Samuel Arey, Jonas Gros

With the expansion of offshore petroleum exploration and extraction activities, validated models are needed to simulate the behaviors of petroleum compounds released in deep (>100 m) waters. We developed a thermodynamic model of the gas-liquid-water partit ...

2016

SmB6 electron-phonon coupling constant from time- and angle-resolved photoelectron spectroscopy

Alberto Crepaldi, Emmanouil Frantzeskakis

SmB6 is a mixed valence Kondo system resulting from the hybridization between localized f electrons and delocalized d electrons. We have investigated its out-of-equilibrium electron dynamics by means of time- and angle-resolved photoelectron spectroscopy. ...

Amer Physical Soc2016

Ba3MxTi3-xO9 (M = Ir, Rh): A family of 5d/4d-based diluted quantum spin liquids

Henrik Moodysson Rønnow, Paul Gregory Freeman

We report the structural and magnetic properties of the 4d (M = Rh) based and 5d ( M = Ir) based systems Ba3MxTi3-xO9 ( nominally x = 0.5, 1). The studied compositions were found to crystallize in a hexagonal structure with the centrosymmetric space group ...

Amer Physical Soc2016

Accessing and predicting the kinetic profiles of homogeneous catalysts from volcano plots

Matthew Wodrich, Michael Markus Busch

Volcano plots are frequently used as aids in the search for new heterogeneous and electrochemical catalysts. These tools successfully predict catalytic processes based solely on thermodynamic descriptions, which also capably describe many aspects of the ca ...

Royal Soc Chemistry2016

Simulating the aqueous dissolution of petroleum emitted into the Gulf of Mexico during the 2010 Deepwater Horizon disaster

Jeremy Samuel Arey, Jonas Gros

What are the processes that entrapped more than 100 000 tons of emitted petroleum compounds in the deep waters of the Gulf of Mexico during the 2010 Deepwater Horizon disaster? We developed a thermodynamic model of the gas-liquid-water partitioning, densit ...

2016

Thermodynamic properties of highly frustrated quantum spin ladders: Influence of many-particle bound states

Frédéric Mila, Bruce Normand

Quantum antiferromagnets have proven to be some of the cleanest realizations available for theoretical, numerical, and experimental studies of quantum fluctuation effects. At finite temperatures, however, the additional effects of thermal fluctuations in t ...

2016

Robust metastable skyrmions and their triangular-square lattice structural transition in a high-temperature chiral magnet

Henrik Moodysson Rønnow, Jonathan White

Skyrmions, topologically protected nanometric spin vortices, are being investigated extensively in various magnets(1-11). Among them, many structurally chiral cubic magnets host the triangular-lattice skyrmion crystal (SkX) as the thermodynamic equilibrium ...

Nature Publishing Group2016

Spin Caloritronics, origin and outlook

Jean-Philippe Ansermet, Sylvain Bréchet, Haiming Yu

Spin caloritronics refers to research efforts in spintronics when a heat current plays a role. In this review, we start out by reviewing the predictions that can be drawn from the thermodynamics of irreversible processes. This serves as a conceptual framew ...

Elsevier2016

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