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A novel reactor based on a bubble column staged by structured catalytic layers with integrated cross flow micro-heat-exchangers (HEX) was designed and tested in the solvent free hydrogenation of 2-methyl-3-butyn-2-ol (MBY) aiming on process intensification ...
U(iv) promotes the disproportionation of otherwise stable uranyl(v) Schiff base complexes affording U(iv)-U(v) oxo clusters with new geometries and the first example of a U(iv)⋯UO 2 + cation-cation interaction. ...
Monitoring, control and optimization of chemical reaction systems often requires in-depth analysis of the underlying reaction mechanisms. This dissertation investigates appropriate tools that facilitate the analysis of homogeneous and gas-liquid reaction s ...
In recent years, higher discharge burn-ups and initial fuel enrichments have led to more and more heterogeneous core configurations in light water reactors (LWRs), especially at the beginning of cycle when fresh fuel assemblies are loaded next to highly bu ...
The photocatalyst for the use in the production of hydrogen from water or aqueous solutions of organic compounds by using light energy, comprises carbon, in addition to a semiconducting photocatalytic material. The photocatalytic apparatus for the producti ...
(The Hydrogen Solar Production Company Limited, UK).2002
Catalytic hydrogenation of NO2- in water to N2 over Pd-supported on different woven fibrous materials was studied. Low porosity C fiber, low porosity D-type glass fiber, and composite (glass covered by g-Al2O3) fiber were used. Pd dispersion was compared f ...
In today's applied light water reactor (LWR) technology, the fissile material is embedded in a ceramic matrix, pressed, and sintered to pellets, which are then filled into the cladding tube of fuel pins that are assembled to a fuel bundle. This is the most ...
A new measurement technique has been developed to determine fission rates in burnt fuel following re-irradiation in a zero-power research reactor The development has been made in the frame of the LIFE@PROTEUS program at the Paul Scherrer Institute which ai ...
In this review ligand exchange and complex formation reactions on fac-[(CO)3M(H2O)3]+ (M = Mn, Tc, Re) and on fac-[(CO)2(NO)Re(H2O)3]2+ are presented. A variety of experimental NMR techniques are described and it is shown that sometimes combinations of tec ...
A theor. anal. is presented for the prediction of the specific energy consumption and the required electrode surface for the electrochem. combustion of org. compds. on synthetic B-doped diamond thin film electrodes. The model is formulated for a perfect mi ...
