Concept

Thermodynamique chimique

Publications associées (35)

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Experimental DSC-based method to determine glass transition temperature during curing of structural adhesives

Thomas Keller, Anastasios Vassilopoulos, Omar Moussa

A new DSC-based experimental method to efficiently establish the glass transition temperature, Tg, vs. curing degree, α, relationship for structural adhesives was developed. The method approaches the continuous Tg-α relationship with a trilinear curve esta ...

Elsevier2012

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The transient liquid crystal technique is widely used for impingement heat transfer experiments. Additionally, due to the difficulty of producing pure temperature steps in the flow, many authors assumed the fluid temperature evolution as a series of step c ...

Institute of Physics2012

The technique of reaction calorimetry adapted for use with reactions in supercritical fluids was used to study some safety aspects of the free-radical dispersion polymerization of methyl methacrylate in scCO2. The reaction heat rate profile was found to ch ...

Wiley-Blackwell2009

Order-disorder phase transition and stress-induced diffusion in Au-Cu

Daniele Mari, Robert Schaller, John Hennig

Isothermal mechanical spectroscopy by means of a forced torsion pendulum (measuring internal friction/mechanical loss) was used to study the interplay of long-range atomic order and stress-induced diffusion (Zener relaxation) in Au57%Cu43%. Our results sho ...

2009

A complete anal. of the heat flow equation in reaction calorimetry with supercrit. fluids is presented. An esp. developed reaction calorimeter is employed to study the challenges introduced by the supercrit. state of the reaction mixt. and the particularit ...

2008

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In this study, the application of reaction calorimetry, an efficient tool to obtain kinetic and safety data, is presented on the free radical dispersion polymn. of MMA in scCO2. The effect of three major parameters with respect to the reaction evolution ar ...

2007

Dispersion polymerization of methyl methacrylate in supercritical carbon dioxide: control of molecular weight distribution by adjusting particle surface area

Thierry Meyer, Charalampos Mantelis

Expts. of Me methacrylate dispersion polymn. are carried out in a reaction calorimeter using PDMS-mMA (methacrylate-terminated polydimethylsiloxane) as surfactant. Different stabilizer concns. from 0 to 10 wt% with respect to monomer have been considered i ...

2007

Supercritical reaction calorimetry: A novel route to supercritical fluid reaction monitoring

Thierry Meyer, Charalampos Mantelis, Frédéric Lavanchy

Supercrit. fluids (SCFs) were intensively studied in the last decade as alternative, environment-friendly benign reaction solvents. A new anal. technique was derived from a combination of classical heat flow reaction calorimetry and the supercrit. fluid te ...

2005

Development of reaction calorimetry applied to supercritical CO2 and methanol-CO2 critical mixture

Frédéric Lavanchy

The combination of reaction calorimetry and supercritical fluids as reactants and/or solvent holds great potential for the optimization of chemical processes using high pressure near-critical and/or supercritical mixtures. The very specific properties of s ...

EPFL2005

Reaction calorimetry in supercritical carbon dioxide - methodology development

Thierry Meyer, Sophie Fortini, Frédéric Lavanchy

Reaction calorimetry is an efficient tool used to obtain kinetic, thermodn. and safety data. A reaction calorimeter, RC1e-HP350, developed in collaboration with Mettler-Toledo GmbH, allows investigating chem. reactions under supercrit. conditions. The main ...

2004