Publications associées à Uranium

Atomic level insight into irradiation effects in nuclear fuel materials

Microstructural evolution during in-pile irradiation, radiation damage effects and fission products behavior in UO2 nuclear fuel are key issues in understanding and for the modeling of the performance as well as safety characteristics of nuclear fuels in t ...

EPFL2024

Implementing Multi-Electron Transfer Strategies in Uranium Chemistry

Dieuwertje Katelijn Modder

In the last decades, the activation of small molecules has attracted increasing attention for their use as cheap and abundant feedstock. Low-oxidation state uranium complexes have displayed high reactivity towards small molecules thanks to their unique pro ...

EPFL2023

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Dieuwertje Katelijn Modder

Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...

Wiley-VCH Verlag GmbH2023

Analysis of the preliminary campaign for the PETALE program

Andreas Pautz, Vincent Pierre Lamirand, Thomas Jean-François Ligonnet, Axel Guy Marie Laureau

The PETALE program aims to provide new experimental data to constrain the stainless steel nuclear data. In this frame, a preliminary measurement campaign has been performed to characterize the neutron flux in key positions of the CROCUS reactor and to deve ...

EDP SCIENCES S A2023

Tuning the reactivity of uranium towards small molecules in multimetallic complexes

Nadir Jori

One of the main goals of organometallic chemistry in the last decades was the activation of small molecule in mild reaction conditions. Even though multiple examples of catalytic cycles able to produce fine chemicals from cheap and abundant sources using t ...

EPFL2023

Multi-electron Transfer by U(II) and Masked U(II) Complexes

Marinella Mazzanti

Complexes of uranium in low oxidation state have shown the ability to activate non-reactive small molecules such as N-2. However, the multi-electron transfer required for such activation remains limited in uranium chemistry. Here, we review our recent rese ...

SWISS CHEMICAL SOC2022

Persistence of the isotopic signature of pentavalent uranium in magnetite

Rizlan Bernier-Latmani, Barbora Bártová, Zezhen Pan

Original data pertaining to the manuscript 'Persistence of the isotopic signature of pentavalent uranium in magnetite' published in Environmental Science and Technology by Zezhen Pan, Yvonne Roebbert, Aaron Beck, Barbora Bartova, Tonya Vitova, Stefan Weyer ...

Zenodo2022

Reactivity of Multimetallic Thorium Nitrides Generated by Reduction of Thorium Azides

Rosario Scopelliti, Marinella Mazzanti, Luciano Barluzzi, Fang-Che Hsueh

Thorium nitrides are likely intermediates in the reported cleavage and functionalization of dinitrogen by molecular thorium complexes and are attractive compounds for the study of multiple bond formation in f-element chemistry, but only one example of thor ...

2022

Biostimulation as a sustainable solution for acid neutralization and uranium immobilization post acidic in-situ recovery

Rizlan Bernier-Latmani, Pierre Rossi, Thomas Coral

Major uranium (U) deposits worldwide are exploited by acid leaching, known as 'in-situ recovery' (ISR). ISR involves the injection of an acid fluid into ore-bearing aquifers and the pumping of the resulting metal-containing solution through cation exchange ...

2022

Persistence of the isotopic signature of pentavalent uranium in magnetite

Rizlan Bernier-Latmani, Barbora Bártová, Zezhen Pan

Uranium isotopic signatures can be harnessed to monitor the reductive remediation of subsurface contamination or to reconstruct paleo-redox environments. However, the mechanistic underpinnings of the isotope fractionation associated with U reduction remain ...

2022