Concept
Uranium
Related publications (114)
A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes
Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic
Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...
2023Biostimulation as a sustainable solution for acid neutralization and uranium immobilization post acidic in-situ recovery
Rizlan Bernier-Latmani, Pierre Rossi, Thomas Coral
Major uranium (U) deposits worldwide are exploited by acid leaching, known as 'in-situ recovery' (ISR). ISR involves the injection of an acid fluid into ore-bearing aquifers and the pumping of the resulting metal-containing solution through cation exchange ...
2022Persistence of the isotopic signature of pentavalent uranium in magnetite
Rizlan Bernier-Latmani, Barbora Bártová, Zezhen Pan
Uranium isotopic signatures can be harnessed to monitor the reductive remediation of subsurface contamination or to reconstruct paleo-redox environments. However, the mechanistic underpinnings of the isotope fractionation associated with U reduction remain ...
2022Design, synthesis, reactivity, and magnetic properties of uranium based oxide and nitride complexes
The activation of small molecules is a paramount challenge in modern chemistry. The use of cheap and abundant molecules such as N2, H2, CO2, or CO as energy supplies or as precursors for fine chemicals production is highly desirable. In particular, the onl ...
EPFL2021