Concept

Dilution isotopique

Publications associées (86)

NanoSIMS applied to the study of foraminifera

Anders Meibom, Stéphane Laurent Escrig, Charlotte Madeleine Nicole Lekieffre, Emmanuelle Geslin

NanoSIMS (Nanoscale Secondary-Ion Mass Spectrometry) is a powerful analytical technique that allows quantitative, subcellular imaging of incorporation and transfer of isotopically labeled compounds and metabolites in biological tissue (Hoppe et al., 2013). ...

2016

Identification of HcgC as a SAM-Dependent Pyridinol Methyltransferase in [Fe]-Hydrogenase Cofactor Biosynthesis

Xile Hu, Lichen Bai, Tao Xu

Previous retrosynthetic and isotope-labeling studies have indicated that biosynthesis of the iron guanylylpyridinol (FeGP) cofactor of [Fe]-hydrogenase requires a methyltransferase. This hypothetical enzyme covalently attaches the methyl group at the 3-pos ...

Wiley-Blackwell2016

First results from recent JET experiments in Hydrogen and Hydrogen-Deuterium plasmas

Henri Weisen, Mikhail Maslov

The hydrogen campaign completed at JET in 2016 has demonstrated isotope ratio control in JET-ILW using gas puffing and pellets for fuelling, Neutral Beam Injection alone or in combination, with D/H spectroscopy as a diagnostic. The plasma properties such ...

2016

Compound-specific carbon, nitrogen, and hydrogen isotope analysis of N-nitrosodimethylamine in aqueous solutions

Urs von Gunten, Stephanie Spahr

Mitigation of N-nitrosodimethylamine (NDMA) and other hazardous water disinfection byproducts (DBP) is currently hampered by a limited understanding of DBP formation mechanisms. Because variations of the stable isotope composition of NDMA can potentially r ...

Amer Chemical Soc2015

Copper isotope evidence for large-scale sulphide fractionation during Earth’s differentiation

James Badro

The differentiation of Earth into a metallic core and silicate mantle left its signature on the chemical and isotopic composition of the bulk silicate Earth (BSE). This is seen in the depletion of siderophile (metal-loving) relative to lithophile (rock-lov ...

2015

Polymorphs of Theophylline Characterized by DNP Enhanced Solid-State NMR

David Lyndon Emsley, Aaron James Rossini, Arthur César Pinon, David Benjamin Roger Antoine Gajan

We show how dynamic nuclear polarization (DNP) enhanced solid-state NMR spectroscopy can be used to characterize polymorphs and solvates of organic solids. We applied DNP to three polymorphs and one hydrated form of the asthma drug molecule theophylline. F ...

American Chemical Society2015

Comparing integrated stable isotope and eddy covariance estimates of water-use efficiency on a Mediterranean successional sequence

Francesco Giuseppe Miglietta

Water-use efficiency (WUE), thought to be a relevant trait for productivity and adaptation to water-limited environments, was estimated for three different ecosystems on the Mediterranean island of Pianosa: Mediterranean macchia (S-MM), transition (S-TR) a ...

Springer Verlag2014

Direct path integral estimators for isotope fractionation ratios

Michele Ceriotti, Bingqing Cheng

Fractionation of isotopes among distinct molecules or phases is a quantum effect which is often exploited to obtain insights on reaction mechanisms, biochemical, geochemical, and atmospheric phenomena. Accurate evaluation of isotope ratios in atomistic sim ...

American Institute of Physics2014

Advances in Structural Elucidation of Small Molecules via High Performance Mass Spectrometry

Konstantin Zhurov

Qualitative and quantitative analyte analysis is omnipresent: from quality control in food, pharmaceutical, biotechnology industries, to new molecular syntheses, detection of explosives and drugs, as well as natural compound mixture analysis, such as crude ...

EPFL2014

Mid-infrared spectroscopy for gases and liquids based on quantum cascade technologies

Nico de Rooij, Hans Peter Herzig, Jérôme Faist, Lubos Hvozdara, Philip Wägli, Yu-Chi Chang

In this paper we present two compact, quantum cascade laser absorption spectroscopy based, sensors developed for trace substance detection in gases and liquids. The gas sensor, in its most integrated version, represents the first system combining a quantum ...

Royal Soc Chemistry2014

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