Concept

Ytterbium

Publications associées (76)

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Lanthanides are versatile modulators of optoelectronic properties owing to their narrow optical emission spectra across the visible and near-infrared range. Their use in metal halide perovskites (MHPs) has recently gained prominence, although their fate in ...

Amer Chemical Soc2024

A fully hybrid integrated erbium-based laser

Tobias Kippenberg, Rui Ning Wang, Andrey Voloshin, Xinru Ji, Zheru Qiu, Andrea Bancora, Yang Liu

Erbium-doped fibre lasers exhibit high coherence and low noise as required for fibre-optic sensing, gyroscopes, LiDAR and optical frequency metrology. Endowing erbium-based gain in photonic integrated circuits can provide a basis for miniaturizing low-nois ...

Nature Portfolio2024

Exploring Photoredox-Catalyzed (Re)functionalizations with Core-Modified Benziodoxolones

Jérôme Waser, Franck Le Vaillant, Stephanie Grace Elizabeth Amos

Alkynes and nitriles are valuable building blocks in organic synthesis and also have multiple applications in chemical biology and materials science. Due to the high availability of tertiary alcohols, developing methods for their conversion into alkynes an ...

WILEY-V C H VERLAG GMBH2022

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A recent 2D spinFET concept proposes to switch electrostatically between two separate sublayers with strong and opposite intrinsic Rashba effects, exploiting the spin-layer-locking mechanism in centrosymmetric materials with local dipole fields. Here, we p ...

AMER CHEMICAL SOC2021

Structure and small molecule activation reactivity of a metallasilsesquioxane of divalent ytterbium

Rosario Scopelliti, Marinella Mazzanti

The first metallasilsesquioxane of a divalent lanthanide, Yb{Cy7Si7O11(OSiMe3)}(THF),1, was synthesized and structurally characterized. The Cy7Si7O11(OSiMe3)(2-)ligands in1bind two Yb(ii) ions in a bridging mode. The dinuclear complex effects the two- ...

ROYAL SOC CHEMISTRY2020

Colorimetry of Luminescent Lanthanide Complexes

Anne-Sophie Chauvin, Julien Alexandre Andres

Europium, terbium, dysprosium, and samarium are the main trivalent lanthanide ions emitting in the visible spectrum. In this work, the potential of these ions for colorimetric applications and colour reproduction was studied. The conversion of spectral dat ...

MDPI2020

Taking lanthanides out of isolation: tuning the optical properties of metal-organic frameworks

Berend Smit, Kevin Sivula, Nestor Guijarro Carratala, Kyriakos Stylianou, Gloria Capano, Andrzej Gladysiak, Christopher Patrick Ireland, Maria Fumanal Quintana, Stavroula Kampouri, Davide Tiana, Samantha Lynn Anderson

Metal organic frameworks (MOFs) are increasingly used in applications that rely on the optical and electronic properties of these materials. These applications require a fundamental understanding on how the structure of these materials, and in particular t ...

2020

CS2 Reductive Coupling to Acetylenedithiolate by a Dinuclear Ytterbium(II) Complex

Rosario Scopelliti, Marinella Mazzanti, Julie Renée Michelle Andrez, Davide Toniolo

The activation of CS2 is of interest in a broad range of fields and more particularly in the context of creating new C‐C bonds. The reaction of the dinuclear ytterbium(II) complex [Yb2L4], 1, (L = (OtBu)3SiO‐) with carbon disulphide led to the isolation of ...

2019

Time- and angle-resolved photoemission spectroscopy of solids in the extreme ultraviolet at 500 kHz repetition rate

Matthias Wolf

Time- and angle-resolved photoemission spectroscopy (trARPES) employing a 500 kHz extreme-ultraviolet light source operating at 21.7 eV probe photon energy is reported. Based on a high-power ytterbium laser, optical parametric chirped pulse amplification, ...

2019

Doping and phase segregation in Mn2+- and Co2+-doped lead halide perovskites from Cs-133 and H-1 NMR relaxation enhancement

Shaik Mohammed Zakeeruddin, David Lyndon Emsley, Dominik Józef Kubicki, Arthur César Pinon, Daniel Prochowicz, Albert Hofstetter, Gabriele Stevanato

Lead halide perovskites belong to a broad class of compounds with appealing optoelectronic and photovoltaic properties. Doping with transition metal ions such as Mn2+ and Co2+ has recently been reported to substantially enhance luminescence and stability o ...

2019

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