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Concept
Acid strength
Résumé
Acid strength is the tendency of an acid, symbolised by the chemical formula HA, to dissociate into a proton, H+, and an anion, A-. The dissociation of a strong acid in solution is effectively complete, except in its most concentrated solutions.
HA -> H+ + A-
Examples of strong acids are hydrochloric acid (HCl), perchloric acid (HClO4), nitric acid (HNO3) and sulfuric acid (H2SO4).
A weak acid is only partially dissociated, with both the undissociated acid and its dissociation products being present, in solution, in equilibrium with each other.
HA H+ + A-
Acetic acid (CH3COOH) is an example of a weak acid. The strength of a weak acid is quantified by its acid dissociation constant, value.
The strength of a weak organic acid may depend on substituent effects. The strength of an inorganic acid is dependent on the oxidation state for the atom to which the proton may be attached. Acid strength is solvent-dependent. For example, hydrogen chloride is a strong acid in aqueous solution, but is a weak acid when dissolved in glacial acetic acid.
The usual measure of the strength of an acid is its acid dissociation constant (), which can be determined experimentally by titration methods. Stronger acids have a larger and a smaller logarithmic constant () than weaker acids. The stronger an acid is, the more easily it loses a proton, H+. Two key factors that contribute to the ease of deprotonation are the polarity of the H-A bond and the size of atom A, which determine the strength of the H-A bond. Acid strengths also depend on the stability of the conjugate base.
While the value measures the tendency of an acidic solute to transfer a proton to a standard solvent (most commonly water or DMSO), the tendency of an acidic solvent to transfer a proton to a reference solute (most commonly a weak aniline base) is measured by its Hammett acidity function, the value. Although these two concepts of acid strength often amount to the same general tendency of a substance to donate a proton, the and values are measures of distinct properties and may occasionally diverge.
Source officielle
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