Pt-group metal (PGM)-free catalysts of the Me-N-C type based on abundant and inexpensive elements have gained importance in the field of oxygen reduction reaction (ORR) electrocatalysis due to their promising ORR-activities. Their insufficient stability, h ...
Planetesimal were the first planetary objects to form in the solar system, which later grew to make the proto-planets. Most of these bodies were differentiated as a result of internal heating. Several differentiated bodies have, then, been accreted followi ...
In this thesis, we exploited optical and X-ray pump-probe methods in a synergistic approach to study the interplay of the electronic, spin and structural degrees of freedom in two class of complex systems relevant for solar energy conversion applications: ...
The thesis focuses on the study of the performance of TBMs in highly jointed and faulted rocks. Despite the great production rates recorded in favourable ground conditions, the TBM advance can be significantly slowed down in limiting geological situations ...
Mineralogy, chemistry and spatial distribution of phyllomanganates, found in abundance at the bottom of thick Ni-laterite deposits, were established on dislocated vein-infillings showing banded and fibrous patterns (i.e. colloforms with rows of tiny boxwor ...
Magnesium partitioning between metal and silicate was experimentally investigated between 34 and 138GPa, 3,500 and 5,450K using laser-heated diamond anvil cells. The 22 measurements are combined with previously published data (total of 49 measurements) to ...
It has been known for decades that certain aqueous salt solutions of LiCl and LiBr readily form glasses when cooled to below approximate to 160 K. This fact has recently been exploited to produce a "salty" high-pressure ice form: When the glass is compress ...
Discontinuous Galerkin (DG) method is presented for numerical modeling of melt migration in a chemically reactive and viscously deforming upwelling mantle column. DG methods for both advection and elliptic equations provide a robust and efficient solution ...
The unique achondrite NWA 7325 is an unusual olivine gabbro composed chiefly of calcic plagioclase (An(85-93)), diopsidic pyroxene (En(50.1-54.0) Wo(44.8-49.3) Fs(0.6-1.3)), and forsteritic olivine (Fo(97)). It is Al and Mg-rich and Fe and Na-poor and disp ...
Crystallization timescales in subvolcanic systems and the consequences of interaction between ascending magmas and gases remain largely unconstrained, as do links between these processes and monitoring signals at restless volcanoes. We apply diffusion chro ...
