Heat transfer physics | EPFL Graph Search

Heat transfer physics describes the kinetics of energy storage, transport, and energy transformation by principal energy carriers: phonons (lattice vibration waves), electrons, fluid particles, and photons. Heat is energy stored in temperature-dependent motion of particles including electrons, atomic nuclei, individual atoms, and molecules. Heat is transferred to and from matter by the principal energy carriers. The state of energy stored within matter, or transported by the carriers, is described by a combination of classical and quantum statistical mechanics. The energy is different made (converted) among various carriers. The heat transfer processes (or kinetics) are governed by the rates at which various related physical phenomena occur, such as (for example) the rate of particle collisions in classical mechanics. These various states and kinetics determine the heat transfer, i.e., the net rate of energy storage or transport. Governing these process from the atomic level (atom or m

Design of Optimized PEDOT‐Based Electrodes for Enhancing Performance of Living Photovoltaics Based on Phototropic Bacteria

Alessandra Antonucci, Ardemis Anoush Boghossian, Sara Politi, Melania Reggente

Living photovoltaics represent a growing class of microbial devices that are based on whole cell–electrode interactions. The limited charge transfer at the cell–electrode interface represents a significant bottleneck in realizing an efficient technology. This study focuses on the development of poly(3,4‐ethylenedioxythiophene) (PEDOT)‐based electrodes that are electrosynthesized in the presence of a sodium dodecyl sulphate (SDS) dopant. Potentiodynamic and potentiostatic electrochemical techniques, as well as scanning electron microscopy (SEM), atomic force microscopy (AFM), Raman spectroscopy, and theoretical modelling of the electropolymerization transient, are employed to create and characterize PEDOT electrodes under various conditions. The electrodes are able to capture photosynthetically derived current under multiple light–dark cycles when interfaced with Synechocystis sp. PCC 6803. In the presence of the Synechocystis, the PEDOT electrodes show a sixfold and twofold enhancement over conventional graphite electrodes for both mediatorless and K3Fe(CN)6‐mediated conditions, respectively. The ability of these electrodes to enhance extracted photocurrent for both direct and indirect electron transfer mechanisms provides a versatile platform for improving various microbial devices.

2020

Ammonia two-phase flow in a horizontal smooth tube: Flow pattern observations, diabatic and adiabatic frictional pressure drops and assessment of prediction methods

Ricardo Lima, Jesus Moreno Quiben, John Richard Thome

The present study illustrates new experimental two-phase flow pattern observations together with diabatic boiling and adiabatic two-phase frictional pressure drop results for ammonia (R7117) flowing inside a 14-mm internal diameter, smooth horizontal stainless steel tube. The flow pattern observations were made for mass velocities of 50, 100 and 160 kg s(-1) m(-2) and saturation temperatures of -14, -2 and 12 degrees C for vapor qualities ranging from 0.05 to 0.6. The flow patterns observed during the study included: stratified-wavy, slug-stratified-wavy, slug, intermittent and annular. For all the experimental conditions, the flow structure observations were compared against the predictions of the flow pattern map model of Wojtan et al. [L. Wojtan, T. Ursenbacher, J.R. Thome, Investigation of flow boiling in horizontal tubes: part I - a new diabatic two-phase How pattern map, Int. J. Heat Mass Transfer 48 (2005) 2955-2969] and showed very good correspondence. The frictional pressure drop measurements were obtained for vapor qualities from 0.05 to 0.6, saturation temperatures from -14 to 14 degrees C, mass velocities from 50 to 160 kg s(-1) m(-2) and heat fluxes from 12 to 25 kW m(-2). The experimental results show the traditional pressure drop trends: the frictional pressure drop increases with vapor quality and mass velocity. Moreover, the results also show that both diabatic and adiabatic frictional pressure drop values are similar, that is, the boiling process in itself does not affect the frictional pressure drop. The correlations of Friedel [L. Friedel, Improved friction drop correlations for horizontal and vertical two-phase pipe flow, in: European Two-Phase Flow Group Meeting, paper E2, Ispra, Italy, 1979], Lockhart and Martinelli [R.W. Lockhart, R.C. Martinelli, Proposed correlation of data for isothermal two-phase two-component in pipes, Chem. Eng. Process 45 (1949) 39-48] and Muller-Steinhagen and Heck [H. Muller-Steinhagen, K. Heck, A simple friction pressure correlation for two-phase flow in pipes, Chem. Eng. Process 20 (1986) 297-308] predicted only 54%, 52% and 60% of the experimental data within +/- 30%, respectively. The correlation of Gronnerud [R. Gronnerud, Investigation of liquid hold-up, flow-resistance and heat transfer in circulation type of evaporators, part iv: two-phase flow resistance in boiling refrigerans, in: Annexe 1972-1, Bull. de I'Inst. Froid, 1979] predicted 93% of the data and the flow pattern based method of Moreno Quiben and Thome [J. Moreno Quiben, J.R. Thome, Flow pattern based two-phase frictional pressure drop model for horizontal tubes. Part II: new phenomenological model, Int.J. Heat Fluid Flow 28 (2007) 1060-1072] predicted more than 97% of the experimental data within the same error band, while the latter method captures almost 89% of the data within +/- 20%. (C) 2008 Elsevier Ltd. All rights reserved.

2009

Contribution to the heat transfer analysis of natural and substitute refrigerants evaporated in a horizontal tube

Olivier Zürcher

The substitution of CFC refrigerants in refrigeration systems, heat pumps and organic Rankine cycles, requests a good knowledge of the heat transfer and pressure drop properties of substitute fluids. A contribution to this international effort is proposed with the study of two hydrofluorocarbon refrigerants (HFC-134a and the zeotropic mixture HFC-407C) and the study of the natural refrigerant ammonia. The HFCs have been experimentally tested on the first test rig developed in the Laboratory of Industrial Energy Systems (LENI) which was substantially modified to cope with ammonia, both in terms of safety requirements and operational conditions. The experimental test section is composed of two concentric tubes, with in tube evaporation of the refrigerant inside the inner tube of counter-current Annular water heating. A new database of the local heat transfer coefficients for the refrigerants HFC-134a, HFC-407C and ammonia together with pressure drop measurements has been collected and used to define and calibrate a new and more general heat transfer model. The two HFC refrigerants have been tested on the test rig developed by Kattan [36]; due to the chemical and the thermophysical properties of ammonia, a new test rig has been designed for the ammonia tests and a new calculation procedure based on the mean temperature measurement on the tube wall has been used. The experimental database covers evaporation tests on plain and on microfin tubes, and with nominal oil concentrations varying from 0 to 5 [%] (by wt.). Detailed modeling is concentrated on the tests on plain tube without oil. Each of the three refrigerants has been evaporated at 4[°C]. The other experimental conditions for the HFCs refrigerants were an inside tube diameter of 10.92[mm], a heat flux range of 2 – 5 [kW/m2] and three mass velocities of G = 100, 200, 300 [kg/(m2s)] visualized as Stratified-Wavy flows (G = 100[kg/(m2s)]), and mainly Annular for the higher mass velocities (G = 200, 300[kg/(m2s)]). The other global conditions for ammonia were an internal tube diameter of 14.00 [mm], a heat flux range of 5 – 70[kW/m2] and eleven mass velocities of G = 10,20,30,40,45,50,55,60,80,120,140[kg/(m2s)], corresponding to Stratified, Stratified-Wavy, Intermittent and Annular flow patterns; complementary tests, varying the mass velocity at constant vapor qualities (x = 20,50,80[%]), have been made in particular to better characterize boundaries between flow patterns. The flow patterns are visualized through glass sections at both ends of the 3.1 [m] long test tube. An extensive review of void fraction models with sensitivity analysis on the actual available flow pattern map has been made. From the 17 correlations reviewed, the models of Taitel-Dukler [71] and Rouhani [79] have been used. Other improvements to the threshold criteria of the Stratified-Wavy to Annular transition, lead to an accurate diabatic map to predict the flow patterns and their transition for very different families of fluids like HFC's and ammonia. A new approach in the prediction of two-phase flow heat transfer has been proposed through the study of each flow pattern separately, according to a new criterion defining the onset of nucleate boiling as a function of the critical convective heat transfer coefficient representative of the location where nucleate boiling might occur. A function based on a pseudo Biot number allows, from the mean heat flux around the tube periphery, to base the model on two different mean heat fluxes applied respectively to the parts of the perimeter in contact with the liquid and the vapor in stratified types of flow. Considering pure convective heat transfer, or mixed convective and nucleate heat transfer, this division allows the use of a common criterion to be applied to each flow pattern. The two-phase flow heat transfer coefficient has finally been obtained as a weighted mean function of the vapor and the liquid heat transfer coefficient with respect to their contact surface with the heated tube. Based on the database of refrigerants HFC-134a and ammonia, the standard deviation of the new heat transfer model is of σ = 27.9[%]. Even if the database showed that the flow conditions were close to, or in the turbulent to laminar flow transition, and even if the major part of the experimental points were purposely obtained close to the various flow pattern transitions, the new model showed very good agreement with the experimental database. Due to the precision of the new flow pattern map and the effectiveness of the onset on nucleate boiling criterion, this new heat transfer model accurately predicts the heat transfer conditions during evaporation. Finally, a new method to model separated flows is proposed, based on partial hydraulic diameters and a mean interface velocity.

EPFL2000