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We study the solution of the two-temperature Fokker-Planck equation and rigorously analyse its convergence towards an explicit non-equilibrium stationary measure for long time and two widely separated time scales. The exponential rates of convergence are e ...
La Suisse attire de nouveaux habitants et la construction à neuf de logements ralentit car l’extraction massive de ressources naturelles n’est plus de mise. Les sphères politiques parlent alors d’une crise du logement qu’il est impératif de résoudre car le ...
Organocatalysis has evolved significantly over the last decades, becoming a pillar of synthetic chemistry, but traditional theoretical approaches based on quantum mechanical computations to investigate reaction mechanisms and provide rationalizations of ca ...
Overprediction of fine-particle ammonium-sulfate molar ratios (R) by thermodynamic models is suggested as evidence for interactions with organic constituents that inhibit the equilibration of gas-phase ammonia with aerosol sulfate and questions the equilib ...
One of the main challenges hampering the development of kinetic models is the lack of kinetic parameters for many enzymatic reactions. Here, the authors introduce a framework to explore the catalytically optimal operating conditions of any complex enzyme m ...
In exothermic, equilibrium-limited processes such as ammonia synthesis, higher per-pass conversions are often achieved by withdrawing the enthalpy of reaction before the conversion has been completed. However, although inter-bed cooling may help controllin ...
Ambitious policies are needed from every country to drastically curtail the anthropogenic emission of greenhouse gases responsible for the on-going modification of the earth's climate. A quick transition towards a society fully based on renewable materials ...
We present a comprehensive study about the relationship between the way detailed balance is broken in non-equilibrium systems and the resulting violations of the fluctuation-dissipation theorem. Starting from stochastic dynamics with both odd and even vari ...
Hsp70 molecular chaperones are abundant ATP-dependent nanomachines that actively reshape non-native, misfolded proteins and assist a wide variety of essential cellular processes. Here, we combine complementary theoretical approaches to elucidate the struct ...
La Ville de Martigny en Valais a été victime à plusieurs reprises de débordements de la Drance, occasionnés par des débâcles glaciaires et des crues à fort charriage. Pour remédier à cette situation de risque important, un projet d’aménagement du cours d’e ...