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LaNi5-type alloys are commercial materials for the negative electrode in Ni-MH rechargeable batteries. Partial substitution of La by mischmetal (Mm) and of Ni by elements like Co, Al, and Mn significantly improve the cycle stability and high-rate discharge ...
The most promising solution towards cementitious materials with a lower carbon footprint is the partial substitution of the clinker by supplementary cementitious materials (SCMs) such as fly ash, blast furnace slag, limestone and calcined clays. The produc ...
Perovskite-derived Ni catalysts offer the remarkable benefit of redox stability that allows their regeneration after deactivation through poisoning or Ni particle growth. Here, the catalytic activity of LaFe0.8Ni0.2O3 towards CO2 methanation was improved b ...
The use of biomass gasification for partially or totally replacing methane in the integrated syngas and ammonia production plant is compared with the performance of the conventional route, typically based on steam methane reforming. However, by undertaking ...
We present a first-principles investigation of the structural, electronic, and magnetic properties of the pristine and Fe-doped alpha-MnO2 using density-functional theory with extended Hubbard functionals. The onsite U and intersite V Hubbard parameters ar ...
Amatoxins are ribosomally synthesized and post-translationally modified bicyclic octapeptides biosynthesized by the deadly basidiomycete fungus Amanita phalloides. Amongst this group, alpha-amanitin is the most widely known toxin and is currently under inv ...
The use of supplementary cementitious materials (SCMs) to replace part of the clinker in cement is the most successful strategy to reduce CO2 emissions in the global cement industry. However, limited supplies of conventional SCMs make it difficult to take ...
Azetidinyl substituents have been recently used to improve the fluorescence quantum yield of several classes of fluorophores. Herein, we demonstrate that other useful photochem. processes can be modulated using this strategy. In particular, we prepd. and m ...
The aim of the present thesis is the development of a new Pt-based bulk metallic glass based on the ternary system of Pt-B-Si that i) complies with the hallmarking standard Pt 850 (i.e. with at least 85 wt.-pct of Pt); ii) provides high hardness (HV>600) a ...
The most prevalent single-nucleotide substitution (SNS) found in cancers is a C-to-T substitution in the CpG motif. It has been proposed that many of these SNSs arise during organismal aging, prior to transformation of a normal cell into a precancerous/can ...