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This review presents an overview of the initial targeted chemical processing stages for conversion of lignocellulosic biomass to platform molecules that serve as intermediates for the production of carbon-based fuels and chemicals. We identify four classes ...
The iodouranium(iii) complex with two hydrotris(3,5-dimethylpyrazolyl) borate ligands is shown to adopt three closely related forms in the solid state. In addition to the previously reported structure for [U(TpMe2) 2I], in which one of the pyrazolyl rings ...
Luminescent polymer latexes loaded with lanthanide complexes have been synthesized by miniemulsion polymerization. A self-assembled europium complex was embedded into poly(methyl methacrylate) nanoparticles without covalent linking and compared to a commer ...
Computing averages over a target probability density by statistical re-weighting of a set of samples with a different distribution is a strategy which is commonly adopted in fields as diverse as atomistic simulation and finance. Here we present a very gene ...
Defined magnetization states in magnetic nanotubes could be the basic building blocks for future memory elements. To date, it has been extremely challenging to measure the magnetic states at the single-nanotube level. We investigate the magnetization state ...
We study the spontaneous curving observed when a strip of tracing paper is deposited on a water surface. The differential swelling across the ribbon thickness leads to a curling of the sheet, with the curvature increasing to a maximum and then relaxing as ...
We present a microfluidic device that enables high throughput production of relatively monodisperse emulsion drops while controlling the average size. The device consists of a two-dimensional array of regularly-spaced posts. Large drops of a highly polydis ...
Two tridentate pyridine-tetrazolate ligands (H 2pytz and H 2pytzc), analogues of the well-known dipicolinate (H 2dpa) ligand, have been synthesized in a straightforward manner and used for lanthanide(iii) coordination. The structures of the resulting tris- ...
The reaction of the UO2+ precursor [(UO 2Py5)(KI2Py2)]n, with the potassium salt of the tetradentate aza β-diketiminate ligand L (L = 2-(4-tolyl)-1,3-bis(quinolyl)malondiiminate) affords the ...
We study theoretically and numerically how hard frictionless particles in random packings can rearrange. We demonstrate the existence of two distinct unstable non-linear modes of rearrangement, both associated with the opening and the closing of contacts. ...
