Concept

Reactivity (chemistry)

Publications associées (53)

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Bent (hetero)allenes such as carbodicarbenes and carbodiphosphoranes can act as neutral C-donor ligands, and diverse applications in coordination chemistry have been reported. N-Heterocyclic diazoolefins are heterocumulenes, which can function in a similar ...

2023

Organic Chemistry and Synthesis Rely More and More upon Catalysts

Pierre Vogel

A few months before the COVID-19 pandemic, Pierre Vogel and Kendall N. Houk published with a new textbook Wiley-VCH, "Organic Chemistry: Theory, Reactivity, and Mechanisms in Modern Synthesis", with a foreword from the late Roberts H. Grubbs. The book demo ...

MDPI2022

Reactivity of Multimetallic Thorium Nitrides Generated by Reduction of Thorium Azides

Rosario Scopelliti, Marinella Mazzanti, Fang-Che Hsueh, Luciano Barluzzi

Thorium nitrides are likely intermediates in the reported cleavage and functionalization of dinitrogen by molecular thorium complexes and are attractive compounds for the study of multiple bond formation in f-element chemistry, but only one example of thor ...

2022

Triazenes have garnered great attention for their anti-cancer properties and versatility in organic chemistry. Recently, a novel synthesis of 1-alkynyl triazenes was reported. This thesis describes the compatibility, reactivity and applications of 1-alkyny ...

EPFL2021

The direct construction of stereogenic axes by enantioselective C-H arylation has been regarded as a very challenging transformation. Very few examples have been reported, despite the indisputable straight-forwardness of the methodology. This is due to the ...

EPFL2021

Aqueous-phase reactive species formed by fine particulate matter from remote forests and polluted urban air

Andrea Mario Arangio, Ting Zhang, Jing Li

In the aqueous phase, fine particulate matter can form reactive species (RS) that influence the aging, properties, and health effects of atmospheric aerosols. In this study, we explore the RS yields of aerosol samples from a remote forest (Hyytiala, Finlan ...

2021

Delivery of a Masked Uranium(II) by an Oxide-Bridged Diuranium(III) Complex

Marinella Mazzanti, Farzaneh Fadaei Tirani

Oxide is an attractive linker for building polymetallic complexes that provide molecular models for metal oxide activity, but studies of these systems are limited to metals in high oxidation states. Herein, we synthesized and characterized the molecular an ...

WILEY-V C H VERLAG GMBH2020

Comparison of the impact of ozone, chlorine dioxide, ferrate and permanganate pre-oxidation on organic disinfection byproduct formation during post-chlorination

Urs von Gunten

Pre-oxidation is commonly used to mitigate the formation of byproducts during post-disinfection. A comparative study of the impact of four pre-oxidants, ozone (O-3), chlorine dioxide (ClO2), permanganate (Mn(vii)) and ferrate (Fe(vi)), on the formation of ...

ROYAL SOC CHEMISTRY2020

Quantum state and surface-site-resolved studies of methane chemisorption by vibrational spectroscopies

Rainer Beck, Ana Gutiérrez González

The combination of quantum state-specific reactant preparation by infrared laser pumping with surface-site-resolved detection of chemisorbed reaction products by Reflection Absorption Infrared Spectroscopy (RAIRS) enables highly detailed studies of molecul ...

2020

Exploring the Chemical Reactivity of Gallium Liquid Metal Nanoparticles in Galvanic Replacement

Raffaella Buonsanti, Seyedehbehnaz Varandili, Dragos-Constantin Stoian, James Richard Pankhurst, Laia Castilla Amorós

Micron/nanosized particles of liquid metals possess intriguing properties and are gaining popularity for applications in various research fields. Nevertheless, the knowledge of their chemistry is still very limited compared to that of other classes of mate ...

AMER CHEMICAL SOC2020

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