The reaction of the tripodal tris-amido U(iii) complex [U(SiMe 2NPh)3-tacn] (tacn = 1,4,7-triazacyclononane), 1, with 0.0625 and 0.25 equiv. of elemental sulfur affords the sulfide-bridged U(iv) complex [U((SiMe2NPh)3-tacn)2(μ-S)], 2, and the terminal pers ...
2014