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H2O2 is a versatile chemical and can be generated by the oxygen reduction reaction (ORR) in proton donor solution in molecular solvents or room temperature ionic liquids (IL). We investigated this reaction at interfaces formed by eleven hydrophobic ILs and ...
We present cryogenic infrared spectra of sodiated beta-cyclodextrin beta-CD + Na, a common cyclic oligosaccharide, and its main dissociation products upon collision-induced dissociation (CID). We characterize the parent ions using high-resolution ion ...
In extension with growing concern to develop new antimicrobial organometallic drugs, an attempt has been made to synthesize five new antimicrobial organotin(IV) carbodithioates with general formula, Me2SnClL (1), Me2SnL2 (2), Et2SnClL (3), Et2SnL2 (4), Bu2 ...
In the present work, photocatalytic degradations of o-nitrophenol (ONP) and p-nitrophenol (PNP) were carried out using CoO-Fe2O3@SiO2@TiO2 nanocomposite as an efficient and cost-effective photocatalyst under simulated solar irradiation. Due to the acid-bas ...
The molecular targeted drug ATRA demands a suitable carrier that delivers to the cancer site due to its poor bioavailability and drug resistance. ATRA, being a lipid with carboxylic acid, has been nano-formulated as a cationic lipo-ATRA with DOTAP:choleste ...
The exploration of highly active bifunctional electrocatalysts for acidic electrochemical water splitting has attracted wide attention due to their importance in polymer electrolyte membrane (PEM) electrolyzers. However, existing catalysts normally suffer ...
Nowadays, molybdenum carbides (Mo2C) represent alternative electrocatalysts to noble metal for the hydrogen evolution reaction (HER). Here, a fast and simple process is proposed for the fabrication of Mo2C-based electrocatalysts on a carbon cloth substrate ...
Tetrel Lewis acids are a prospective alternative to commonly employed neutral boranes in frustrated Lewis pair (FLP) chemistry. While cationic tetrylium Lewis acids, being isolobal and iso(valence)electronic, are a natural replacement to boranes, neutral t ...
In this study, photocatalytic degradation of 2-nitrophenol and 4-nitrophenol were carried out efficiently using ZnO nanoparticles photo-catalyst under simulated solar irradiation. The photo-decomposition processes were optimized simultaneously by employing ...
We investigate the presence of a surface species for the active pharmaceutical ingredient (API) AZD9496 with dynamic nuclear polarization surface enhanced nuclear spectroscopy (DNP SENS). We show that using DNP we can elucidate the presence of an amorphous ...