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Catalytic processes and in particular heterogeneous catalysis are vital for todays industry. However, many industrial catalytic processes require high temperatures and pressures to work efficiently. This stands in contrast to biological catalysts, which fu ...
The methoxylation of p-tert-butyltoluene (TBT) in CH3OH-H2SO4-H2O soln. has been investigated on graphite and boron-doped diamond (BDD) anodes. Different reaction intermediates have been found on BDD and graphite. In fact BDD electrodes favor the formation ...
The reaction of half-sandwich complexes of ruthenium, rhodium, and iridium with amino-substituted 3-hydroxy-2-pyridone ligands in aqueous solution gives monomeric O,O'-chelate complexes. Upon addition of base, the complexes assemble to form trimeric metall ...
This project aims at the optimization of chemical reactions by using online analytical and chemometric methods. The experiments are carried out in a fully automated chemical reactor (1 liter). The host computer controls the standard process variables such ...
A review. Only the most important methods for the generation of organometallic reagents and intermediates are covered in this review. This holds for the reductive insertion of Li into org. halides, the permutational interconversion of org. halides with org ...
The in vivo and in vitro labeling of fusion proteins with synthetic mols. capable of probing and controlling protein function has the potential to become an important method in functional genomics and proteomics. We have recently introduced an approach for ...
We report on a study of B 0 → D(*)0 π+π- decays using 29.1 fb-1 of e+e- annihilation data recorded at the γ(4S) resonance with the Belle detector at the KEKB storage ring. Making no assumptions about the intermediate mechanism, the branching fractions for ...
Microfluidic devices are a promising new tool for studying and optimizing (bio)chemical reactions and analyses. Many (bio)chemical reactions require accurate temperature control, such as for example thermocycling for PCR. Here, a new integrated temperature ...
With a view toward laser isotope separation of Si, we have studied infrared multiphoton dissociation (IRMPD) of room temperature trichlorosilane, SiHCl3. Over the wavelength range investigated, multiphoton dissociation of the room temperature species exhib ...
Combinatorial mutagenesis was used to investigate the role of three key residues in cytochrome c peroxidase (CCP) from Saccharomyces cerevisiae, Arg48, Trp51, and Trp191, in control of the reactivity and selectivity of the heme-contg. enzyme. Libraries wer ...
