Publications associées à Metal extrême

Optical absorption properties of metal-organic frameworks: solid stateversusmolecular perspective

Berend Smit, Ivano Tavernelli, Anne-Clémence Corminboeuf, Maria Fumanal Quintana

The vast chemical space of metal and ligand combinations in Transition Metal Complexes (TMCs) gives rise to a rich variety of electronic excited states with local and non-local character such as intra-ligand (IL), metal-centered (MC), metal-to-ligand (MLCT ...

2020

Heat-transfer at the interface between a metal and a non-metal: influence of ultra-thin interlayers, interface chemistry and atomic order

Maïté Blank

The Thermal Boundary Conductance (TBC) at the interface between metals and dielectrics is of key importance for heat transport in structures heterogeneous on a scale from 100 µm downwards. In this thesis the TBC of a large number of metal/dielectric couple ...

EPFL2019

Varying the metal to ethacrynic acid ratio in ruthenium(ii)/osmium(ii)-p-cymene conjugates

Paul Joseph Dyson, Catherine Marie Amélie Clavel, Mylène Soudani, Emilia Paunescu

Following the identification of a ruthenium(II)-arene complex with an ethacrynic acid-modified imidazole ligand, which inhibits glutathione transferase (GST) and is cytotoxic to chemo-resistant cancer cells, a series of structurally related ruthenium(II)- ...

Elsevier2017

Suppressing Nucleation in Metal–Organic Chemical Vapor Deposition of MoS2

Andras Kis, Dmitry Ovchinnikov, Dmitrii Unuchek, Hokwon Kim, Davide Deiana

Toward the large-area deposition of MoS2 layers, we employ metal–organic precursors of Mo and S for a facile and reproducible van der Waals epitaxy on c-plane sapphire. Exposing c-sapphire substrates to alkali metal halide salts such as KI or NaCl together ...

American Chemical Society (ACS)2017

Photo-transformation of pedogenic humic acid and consequences for Cd(II), Cu(II) and Pb(II) speciation and bioavailability to green microalga

Pascal Miéville

Humic substances (HS) play key role in toxic metal binding and protecting aquatic microorganisms from metal-induced stress. Any environmental changes that could alter HS concentration and reactivity can be expected to modify metal complexation and thus aff ...

Pergamon-Elsevier Science Ltd2015

Two-Dimensional Metal-Organic Networks as a New Class of Electrocatalysts

Benjamin Wurster

This thesis deals with the electrocatalytic properties of two-dimensional metal organic coordination networks (2D-MOCNs) self-assembled on electrode surfaces and catalytic activity of 2D-MOCNs is demonstrated for the first time. The low-coordinated metal c ...

EPFL2015

Ultrafast Photophysics of Transition Metal Complexes

Majed Chergui

CONSPECTUS: The properties of transition metal complexes are interesting not only for their potential applications in solar energy conversion, OLEDs, molecular electronics, biology, photochemistry, etc. but also for their fascinating photophysical properti ...

American Chemical Society2015

Porous metal article and method of producing a porous metal article

Andreas Mortensen

A process for producing a metal article containing at least 10% interconnected porosity, using a preform (11), comprising: mixing an organic binder, a wetting agent and a granular material, to obtain a mouldable paste that combines 10 vol. pct. or more of ...

2012

Fatigue and cyclic creep of replicated microcellular aluminium

Andreas Mortensen, Frédéric Diologent, Sébastien Philippe Soubielle

The cyclic behaviour of 400 mu m pore size replicated aluminium foam is assessed in tension-tension fatigue with a stress ratio equal to 0.1, keeping the load amplitude constant, for relative density values comprised between 0.175 and 0.220. The number of ...

Elsevier2011

Preform to produce metallic foam

Andreas Mortensen

A process for producing a metal article containing at least 10% interconnected porosity, using a preform (11), comprising: mixing an organic binder, a wetting agent and a granular material, to obtain a mouldable paste that combines 10 vol. pct. or more of ...

2010