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Five increasingly sophisticated aromaticity indexes, based on nucleus-independent chem. shifts (NICS), were evaluated against a uniform set of arom. stabilization energies (ASE) for 75 mono- and polyheterocyclic five-membered rings. While acceptable statis ...
In life-cycle assessment (LCA), it is desirable to compare quantities of chemicals released into the environment in terms of the risk and consequences of toxicological effects. Many current methods rely directly on adaptations of regulatory-orientated appr ...
Interest in the biodegradation mechanisms and environmental fate of polycyclic aromatic hydrocarbons (PAHs) is motivated by their ubiquitous distribution, their low bioavailability and high persistence in soil, and their potentially deleterious effect on h ...
A rapid transformation of eicosapentaenoic acid is initiated upon disintegration of cells of the marine diatom Stephanopyxis turris. In contrast to any other fatty acid cleaving activity known, this diatom releases a blend of chlorinated C8-hydrocarbons in ...
Pollution by polycyclic aromatic hydrocarbons (PAHs) is widespread due to unsuitable disposal of industrial waste. They are mostly defined as priority pollutants by environmental protection authorities worldwide. Phenanthrene, a typical PAH, was selected a ...
This study is the first thorough method optimisation for accelerated solvent extraction (ASE) of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) from chemically dried compost. For PCBs, optimised solvent composition, temperatur ...
Composting (aerobic treatment of organic wastes) and digestion (anaerobic treatment of organic wastes combined with biogas production) are important waste management strategies with increasing significance in the European Union and Switzerland. Most of the ...
Organics found in comet 81P/ Wild 2 samples show a heterogeneous and unequilibrated distribution in abundance and composition. Some organics are similar, but not identical, to those in interplanetary dust particles and carbonaceous meteorites. A class of a ...
All twelve indolecarboxylic acids carrying both a fluorine substituent and a carboxy group at the benzo ring have been prepd. either directly from the corresponding fluoroindoles or from the chlorinated derivs. by hydrogen/metal permutation ("metalation"), ...
he influence of the halogen upon the TiO2 photocatalytic degradation of p-halophenols in water has been investigated. Phenol was used as the reference compound. Compared with its value for phenol, the apparent first-order rate constant of removal, k, was s ...
