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Small molecule donor/polymer acceptor bulk-heterojunction films with both compounds strongly absorbing have great potential for further enhancement of the performance of organic solar cells. By employing a newly synthesized small molecule donor with a comm ...
Two new triazole-pyridine-bistetrazolate ligands were synthesized via a versatile procedure that allows for further derivatization; their corresponding homoleptic tris-ligand nona-coordinated lanthanide complexes are highly luminescent in the solid state a ...
We study the ligand-field splittings and magnetic properties of three Er-III single-ion magnets which differ in the peripheral ligand sphere but exhibit similar first coordination spheres by inelastic neutron scattering (INS) and SQUID magnetometry. The IN ...
Magnetic properties of single crystal beta-TeVO4 with a zigzag chain of magnetic centers (V4+ ions, S = 1/2) are analyzed in the framework of the J(1)-J(2) model. The best agreement with experimental data is obtained for the J(1)-J(2) model with parameters ...
Low-temperature x-ray magnetic circular dichroism measurements on the endohedral single-molecule magnet DySc2N@C-80 at the Dy M-4,M-5 edges reveal a shrinking of the opening of the observed hysteresis with increasing x-ray flux. Time-dependent measurements ...
By ab initio many-body quantum chemistry calculations, we determine the strength of the symmetric anisotropy in the 5d5 j ~ 1/2 layered material Ba2IrO4. While the calculated anisotropic couplings come out in the range of a few meV, orders of magnitude str ...
Using infinite projected entangled-pair states, we show that the Shastry-Sutherland model in an external magnetic field has low-magnetization plateaus which, in contrast to previous predictions, correspond to crystals of bound states of triplets, and not t ...
A family of lanthanide complexes has been synthesized by the subcomponent self-assembly methodology. Molecular architectures, which were stable in solution and under ambient conditions, were designed by the in situ formation of ligands around lanthanide io ...
Two luminescent terbium and europium lanthanide chelates were efficiently embedded into silica nanoparticles by using a reverse microemulsion process. The incorporation was achieved without covalent bonding between the lanthanide chelates and the silica ma ...
We have studied the fluoride-bridged Dy-Cr molecular nanomagnet [Dy(hfac)(4)-CrF2(py)(4)]center dot 1/2CHCl(3) by x-ray magnetic circular dichroism (XMCD). The obtained element-specific magnetization curves allow for a quantification of the sign and streng ...
