Concept

Applied spectroscopy

Publications associées (274)

Structural, optical and crystal field analyses of undoped and Mn2+-doped ZnS nanoparticles synthesized via reverse micelle route

Zinc sulfide, both as a bulk material and in nanocrystalline form, is a valuable luminescent material with important applications. Doped ZnS nanoparticles of around 5 nm are the material of choice for optoelectronic applications running in the UV region ow ...

Elsevier Science Bv2014

The influence of RAPTA moieties on the antiproliferative activity of peripheral-functionalised poly(salicyladiminato) metallodendrimer

Paul Joseph Dyson, Catherine Marie Amélie Clavel

Cationic N,O-chelating dendrimers functionalised on the periphery with RAPTA-like (ruthenium(II)-arene-1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane) moieties have been synthesised and characterised using NMR and IR spectroscopy, elemental analysis and MAL ...

Royal Society of Chemistry2013

Methane Reacts with Heteropolyacids Chemisorbed on Silica to Produce Acetic Acid under Soft Conditions

David Lyndon Emsley, Aaron James Rossini, Jeremie Pelletier

Selective functionalization of methane at moderate temperature is of crucial economic, environmental, and scientific importance. Here, we report that methane reacts with heteropolyacids (HPAs) chemisorbed on silica to produce acetic acid under soft conditi ...

AMER CHEMICAL SOC2013

Structural models of activated gamma-alumina surfaces revisited: Thermodynamics, NMR and IR spectroscopies from ab initio calculations

The activation of highly catalytic gamma-alumina surfaces by thermal treatment and the description of the related chemical processes at atomic scale is a topical issue. According to a recent study [J. Am. Chem. Soc. 134 (2012) 14430], the enhanced reactivi ...

Elsevier Science Bv2013

Arene ruthenium complexes with phosphinoferrocene amino acid conjugates: Synthesis, characterization and cytotoxicity

Paul Joseph Dyson, Olivier Pierre Zava

A series of heterodinuclear p-cymene ruthenium ferrocene complexes, [(eta(6)-p-MeC6H4Pri)RuCl2(Ph(2)Pfc-CONHRCO2Me-kappa P)] (R = (S)-Me: 6, R = (S)-CHMe2: 7, R = (S)-CH2OMe: 8, R = (S)-CH2SMe: 9, R = (S)-CH2CH2CO2Me: 10) have been synthesized from p-cymen ...

Elsevier Science Sa2013

High temperature transformations in a steel-TiCN cermet

Daniele Mari

The influence of the carbon content on the microstructure, phase transformation and hardness of an iron-based cermet is studied. The cermet is constituted by a high-alloyed steel as matrix, and TiCN particles (50 vol.%) as reinforcement. The material is pr ...

Elsevier Sci Ltd2013

The metastable HCl center dot 6H(2)O phase - IR spectroscopy, phase transitions and kinetic/thermodynamic properties in the range 170-205 K

Michel Rossi, Simone Chiesa

In this laboratory study a multidiagnostic experimental approach including Fourier transform infrared (FTIR) absorption of 1 to 2 mu m thick polycrystalline ice films, residual gas mass spectrometry (MS) and total pressure measurement were employed. Both a ...

Copernicus Gesellschaft Mbh2013

Grain boundary formation stages in a deformed yellow gold single crystal studied by mechanical spectroscopy

Daniele Mari, Robert Schaller, Iva Tkalcec Vâju

A monocrystalline 18-carat yellow gold sample is deformed stepwise from 2% to 12% at room temperature. The mechanical loss spectrum is recorded and analysed. At low deformations the exponential high temperature background increases. At a critical deformati ...

Elsevier Science Sa2013

Polymer based single mode optical waveguide for spectroscopy applications

Hans Peter Herzig, Irène Antoinette Philipoussis, Toralf Scharf, Maurine Malak Karam Awadallah

In this work, we present for the first time, two dimensional low loss single mode optical waveguides fabricated with EPO materials. The waveguide geometry has a rectangular shape and it is buried between two EPOCLAD layers. Its refractive index distributio ...

Spie-Int Soc Optical Engineering2013

Synthesis and Phase Stability of Metastable Bixbyite V2O3 Colloidal Nanocrystals

Raffaella Buonsanti

We have recently developed a colloidal route to vanadium sesquioxide (V2O3) nanocrystals with a metastable bixbyite crystal structure. In addn. to being one of the first reported observations of the bixbyite phase in V2O3, it is also one of the first succe ...

2013

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