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A new spin on C60: Axially chiral, pushpull buta-1,3-diene chromophores conjugated to vicinally methylated fullerenes (see picture) have high barriers of rotation about their chiral axes. These high barriers allowed their optical resolution and the determi ...
We synthesized AuPt alloyed nanoparticles in colloidal solution by a one-pot procedure based on synchrotron x-ray irradiation in the presence of PEG (polyethylene glycol). The exclusive presence of alloyed nanoparticles with fcc structure was confirmed by ...
We have used s- and p-polarized synchrotron radiation to image the electronic structure of epitaxial graphene near the (K) over bar point by angle-resolved photoemission spectroscopy (ARPES). Part of the experimental Fermi surface is suppressed due to the ...
Half-vortices have been recently shown to be the elementary topological defects supported by a spinor cavity exciton-polariton condensates with spin-anisotropic interactions [Y. G. Rubo, Phys. Rev. Lett. 99, 106401 (2007)]. A half-vortex is composed by an ...
The Bingel addn. of a trimalonate derived from a chiral, cyclotriveratrylene (CTV)-based tripodal tether to C60 was reinvestigated. The present use of enantiomerically pure (P)- and (M)-configured CTV units in the tether allowed the isolation of a total of ...
Both enantiomers of an optically active trialkynyl(phenyl)methane (the key building blocks in the construction of a stable expanded cubane) have been prepd. The strategy involved the resoln. of a racemic intermediate by means of HPLC on a chiral stationary ...
We study second harmonic generation (SHG) from noncentrosymmetric nanocrystals under linearly polarized (LP) and circularly polarized (CP) excitations. Theoretical models are developed for SHG from nanocrystals under both plane-wave and focused excitations ...
A series of cationic metalla-rectangles of the general formula [(p-cymene)4Os4(OO.intrsec.OO)2(N.intrsec.N)2]4+ have been obtained in methanol from the dinuclear arene osmium precursors [(p-cymene)2Os2(OO.intrsec.OO)2Cl2] (OO.intrsec.OO = 2,5-dihydroxy-1,4 ...
By performing pump-probe experiments, we study the relaxation dynamics of spin-polarized excitons in a wurtzite GaN/AlGaN quantum well (QW)grown by metal organic vapor phase epitaxy. The circular degree of polarization of the differential reflectivity sign ...
The magnetic properties of individual Fe and Co atoms as well as of small Fe clusters adsorbed on two atomic layers of Al2O3 grown on Ni3Al(111) have been investigated by x-ray absorption spectroscopy and x-ray magnetic circular dichroism. We find ratios o ...