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The formation of either dinuclear double-stranded or pentanuclear circular helicates from a ligand containing two tridentate domains separated by a phenylene unit can be controlled by inter-ligand steric interactions which themselves are governed by the si ...
The heterobitopic ligands LAB4 and LAB5 have been designed and synthesised with the ultimate aim of self-assembling dual-function lanthanide complexes containing either a magnetic and a luminescent probe or two luminescent probes emitting at different wave ...
Light water reactor (LWR) neutronics codes and cross-section libraries need further qualification when used for the calculation of inert matrix fuel (IMF) cells. Three types of validation efforts have been undertaken for the PuO2-Er2O3-ZrO2 IMF concept und ...
The reproducible synthesis of the unusual ionic aluminum compd. [Tl3F2Al(OR)3]+[Al(OR)4]- (1) is reported. In the reaction of Li[Al(OR)4] [R = C(H)(CF3)2] with TlF the initially desired Tl[Al(OR)4] only formed with an exact 1:1 stoichiometry, while an exce ...
The incorporation of up to 40 % lead excess into the perovskite lattice of Pb(Zr,Ti)O-3 (PZT) has been investigated. Three independent chemical composition analysis methods confirmed the correct determination of the lead excess, present as Pb2O3. High reso ...
