Publications associées à Bicarbonate buffer system

Oxidation of organic micropollutant surrogate functional groups with peracetic acid activated by aqueous Co(II), Cu(II), or Ag(I) and geopolymer-supported Co(II)

Peracetic acid (PAA) in combination with transition metals has recently gained increasing attention for organic micropollutant abatement. In this study, aqueous Co(II), Cu(II), and Ag(I) were compared for their capacity to activate PAA. Co(II) outperformed ...

PERGAMON-ELSEVIER SCIENCE LTD2022

Catalytic effects of photogenerated Fe(II) on the ligand-controlled dissolution of Iron(hydr)oxides by EDTA and DFOB

Janet Gordon Hering

Low bioavailability of iron due to poor solubility of iron(hydr)oxides limits the growth of microorganisms and plants in soils and aquatic environments. Previous studies described accelerated dissolution of iron(hydr)oxides under continuous illumination, b ...

Pergamon-Elsevier Science Ltd2021

High-throughput cryogenic spectroscopy for glycan analysis

Thomas Rizzo, Ahmed Ben Faleh, Stephan Warnke, Valeriu Scutelnic

A method for analyzing a plurality of molecules with cryogenic vibrational spectroscopy including the steps of providing a packet of molecules in a ionized form, injecting the packet into an ion mobility section, spatially separating the ions of the packet ...

2019

Feasibility study of a CO2-based system in NEST

François Maréchal, Luc Girardin, Raluca-Ancuta Suciu

The NEST building laboratory of Empa and Eawag is a modular research and innovation demonstrator where new technologies, materials and systems are tested, researched, honed and validated in realistic conditions. In the NEST concept, only the supporting str ...

Industrial Process and Energy Systems Engineering Group, EPFL Valais Wallis2017

Safety issues of a CO2-based System in NEST

Luc Girardin, François Maréchal, Samuel Henchoz

This study addresses the safety issue for the realization of a CO2 heat distribution system in the NEST research and innovation building. It is based on consideration around the concept of CO2 network developed at LENI/IPESE-EPFL and takes advantage from t ...

IPSE-EPFL Valais-Wallis2016

Influence of bicarbonate ions on the deterioration of mortar bars in sulfate solutions

Karen Scrivener, Barbara Lothenbach, Wolfgang Kunther

This work investigates the influence of bicarbonate ions on the deterioration of cementitious material exposed to sulfate ions. Mortars based on a CEM I and on a CEM III/B cement were investigated. Experimental investigations were compared to thermodynamic ...

Pergamon-Elsevier Science Ltd2013

Electrokinetic supercharging for highly efficient peptide preconcentration in capillary zone electrophoresis

Hubert Girault

Electrokinetic supercharging has been integrated in CZE for the development of a highly sensitive methodology for protein tryptic digest analysis. A careful choice of the experimental conditions led to sensitivity enhancement factors between 1000 and 10 00 ...

2008

Aqueous phase carbon dioxide and bicarbonate hydrogenation catalyzed by cyclopentadienyl ruthenium complexes

Paul Joseph Dyson, Gabor Laurenczy, Antoine Dorcier

The water-sol. ruthenium(II) complexes [Cp'RuX(PTA)2]Y and [CpRuCl(PPh3)(mPTA)]OTf (Cp' = Cp, Cp*, X = Cl and Y = nil; or X = MeCN and Y = PF6; PTA = 1,3,5-triaza-7-phosphaadamantane; mPTA = 1-methyl-1,3,5-triaza-7-phosphaadamantane) were used as catalyst ...

2007