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Concept
Groupe 14 du tableau périodique
Résumé
The carbon group is a periodic table group consisting of carbon (C), silicon (Si), germanium (Ge), tin (Sn), lead (Pb), and flerovium (Fl). It lies within the p-block.
In modern IUPAC notation, it is called group 14. In the field of semiconductor physics, it is still universally called group IV. The group is also known as the tetrels (from the Greek word tetra, which means four), stemming from the Roman numeral IV in the group names, or (not coincidentally) from the fact that these elements have four valence electrons (see below). They are also known as the crystallogens or adamantogens.
Like other groups, the members of this family show patterns in electron configuration, especially in the outermost shells, resulting in trends in chemical behavior:
Each of the elements in this group has 4 electrons in its outer shell. An isolated, neutral group 14 atom has the s2 p2 configuration in the ground state. These elements, especially carbon and silicon, have a strong propensity for covalent bonding, which usually brings the outer shell to eight electrons. Bonds in these elements often lead to hybridisation where distinct s and p characters of the orbitals are erased. For single bonds, a typical arrangement has four pairs of sp3 electrons, although other cases exist too, such as three sp2 pairs in graphene and graphite. Double bonds are characteristic for carbon (alkenes, ...); the same for π-systems in general. The tendency to lose electrons increases as the size of the atom increases, as it does with increasing atomic number.
Carbon alone forms negative ions, in the form of carbide (C4−) ions.
Silicon and germanium, both metalloids, each can form +4 ions.
Tin and lead both are metals, while flerovium is a synthetic, radioactive (its half life is very short, only 1.9 seconds) element that may have a few noble gas-like properties, though it is still most likely a post-transition metal. Tin and lead are both capable of forming +2 ions. Although tin is chemically a metal, its α allotrope looks more like germanium than like a metal and it is a poor electric conductor.
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