Publications associées à Groupe 14 du tableau périodique

Synthesis, isolation and application of a sila-ketenyl anion

Ynolates or ketenyl anions, [RCCO]-, are negatively charged reactive intermediates, which can be generated in situ and used for divergent chemical transformations. Ynolates can react either at the oxygen or carbon centres or across the C-C triple bond, mak ...

Springernature2023

Influence of aerosol acidity and organic ligands on transition metal solubility and oxidative potential of fine particulate matter in urban environments

Athanasios Nenes, Gerhard Lammel

The adverse health effects of air pollution around the world have been associated with the inhalation of fine particulate matter (PM2.5). Such outcomes are thought to be related to the induction of oxidative stress due to the excess formation of reactive o ...

Elsevier2023

Multipolar expansions for scattering and optical force calculations beyond the long wavelength approximation

Olivier Martin, Karim Achouri, Andrei Kiselev, Marco Riccardi

We review three different approaches for the calculation of electromagnetic multipoles, namely, the Cartesian primitive multipoles, the Cartesian irreducible multipoles, and the spherical multipoles. We identify the latter as the best suited to describe th ...

AMER PHYSICAL SOC2022

Towards implementing new isotopes for environmental research:Redetermination of the 32Si half-life

Mario Aaron Veicht

The predicted climate changes on Earth will significantly impact the environment and human society. The climate patterns observed during the past centuries led to a better understanding of the driving forces for such changes. However, more studies using ne ...

EPFL2022

Elucidating the present-day chemical composition, seasonality and source regions of climate-relevant aerosols across the Arctic land surface

Julia Schmale, Imad El Haddad

The Arctic is warming two to three times faster than the global average, and the role of aerosols is not well constrained. Aerosol number concentrations can be very low in remote environments, rendering local cloud radiative properties highly sensitive to ...

IOP Publishing Ltd2022

One- and two-step semi-Lagrangian integrators for arbitrary Lagrangian-Eulerian-finite element two-phase flow simulations

John Richard Thome, Gustavo Rabello Dos Anjos, Gustavo Charles Peixoto de Oliveira

Semi-Lagrangian (SL) schemes are of utmost relevance to simulate two-phase flows where advection dominates. The combination of SL schemes with the finite element (FE) method and arbitrary Lagrangian-Eulerian (ALE) dynamic meshes yields a strong ingredient ...

WILEY2022

THz characterization of GeSn monocrystalline thin films

Anna Fontcuberta i Morral, Andrea Giunto, Nicolas Philippe Laurent Humblot

The employment of other group IV materials, such as alloys of germanium and tin, poses a solution for overcoming the efficiency limit of silicon that arises from its indirect bandgap. By using THz spectroscopy, the optoelectronic properties, such as conduc ...

IEEE2022

Rh-catalyzed C-H Bond Heteroarylation with Hypervalent Iodine Reagents and Pd-Catalyzed Tethered Functionalizations of Carbon-Carbon Multiple Bonds

Ashis Kumar Das

Transition metal-catalyzed C-H activation is a powerful tool for the synthesis of organic building blocks, materials, and natural products. Over the last decade, directing-group-assisted metal-catalyzed C-H functionalization has attracted increasing intere ...

EPFL2022

On the relevance of P poisoning in real-world DOC aging

Oliver Kröcher, Davide Ferri

Understanding the real aging of Diesel oxidation catalysts (DOC) is key to predict their useful lifetime. This work comprises a detailed study of a commercial DOC in its unused state and after use in vehicle for 288,000 km. The activity of the samples was ...

ELSEVIER2021

Optical gap and fundamental gap of oligoynes and carbyne

Anne-Clémence Corminboeuf, Holger Frauenrath, Jan Cornelius Brauer, Stephen Schrettl, Laurent Alexis Clément Vannay, Eric Albert Georges Bremond, Emmanuel Romaric Contal

The optoelectronic properties of various carbon allotropes and nanomaterials have been well established, while the purely sp-hybridized carbyne remains synthetically inaccessible. Its properties have therefore frequently been extrapolated from those of def ...

Nature Research2020