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A combined DFT/vibrational spectroscopy approach is used to determine the interactions of the 1,3-dimethylimidazolium ([Mmim]+) and 1-ethyl-3-methylimidazolium ([Emim]+) cations and [BF4]- anions with each other in the liquid state and with Pd nanoparticle ...
Heteronuclear Au–Pd nanoparticles were prepared and immobilized in the functionalized ionic liquid [C2OHmim][NTf2]. The structural and electronic properties of the nanoparticles were characterized by a range of techniques and the surface of the nanoparticl ...
Pd nanoparticles (NPs) with a small size and narrow size distribution were prepared from the decomposition of Pd(OAc)(2) in a series of hydroxyl-functionalized ionic liquids (ILs) comprising the 1-(2'-hydroxylethyl)-3-methylimidazolium cation and various a ...
Platinum nanoparticles (PtNPs stabilized by an ionic-liq.-like-copolymer (IP) immobilized in various ionic liqs. (ILs)) effectively catalyze the selective hydrogenation of arom. chloronitro compds. to arom. chloroamines, a reaction of considerable com. sig ...