Synthesis and crystallographic characterisation of the heterodimetallic complex [(dibenzo-18-crown-6)K(m-Cl)3Ru(h6-p-cymene)]
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Cerium(III) and cerium(IV) both form formate complexes. However, the species in aqueous solution and the solid-state structures are surprisingly different. Ce(III) shows only mononuclear complexes in aqueous solution, whereas Ce(IV) forms a stable hexanucl ...
The synthesis of the first π-extended tetrathiafulvalene (TTF) ligand featuring a furanoquinonoid spacer and pyridyl functional groups is described. This compound shows an unprecedented electrochemical sensing behavior and excellent coordinating properties ...
The first solid-state structures of complexed P3N3X6 (X=halogen) are reported for X=Cl. The compounds were obtained from P3N3Cl6 and Ag[Al(OR)4] salts in CH2Cl2/CS2 solution. The very weakly coordinating anion with R=C(CF3)3 led to the salt Ag(P3N3Cl6)2+[A ...
Tert-butyl-substituted diethynylallenes (DEAs) are ideal for the construction of novel topologies because undesirable reactions on the cumulenic moiety are suppressed. The authors developed the asym. synthesis of two shape-persistent enantiopure alleno-ace ...
New heterobinuclear lanthanide complexes with benzoxazole-substituted 8-hydroxyquinolines, [Ln(ligand)2(μ-ligand)2Na] (Ln: Yb, Lu), have been prepared and their structure established by X-ray crystallography, 1H NMR spectroscopy, and photophysical studies. ...
A series of mono-, di-, and trinuclear organometallic alkynyl phosphane gold(I) complexes contg. the stable and water-sol. PTA and DAPTA ligands have been synthesized and characterized. The solid-state structure of one of these compds. was also established ...
Micro-mechanical systems are exquisite tools for high-resolution surface patterning. As an alternative to traditional photolithography, they can be used for local material deposition at the sub-100 nm scale. This can be either done by means of liquid dispe ...
Polaritons are an odd cross-breed of a particle, half-matter, half-light. They could offer an abundant crop of new and improved optoelectronic devices — a promise already being fulfilled. ...
Several nitrosyl complexes of Fe and Co have been prepared using the sterically hindered Ar-nacnac ligand (Ar-nacnac = anion of [(2,6- diisopropylphenyl)NC(Me)]2CH). The dinitrosyliron complexes [Fe(NO)2(Ar-nacnac)] (1) and (Bu4N)[Fe(NO) 2(Ar-nacnac)] (2) ...
A series of salts composed of the coordinatively unsatd. areneruthenium β-diketiminato cation and different anions, [(η6-C6H6)Ru(ArN:CMeCHCMe:NAr)][X] (1-4; Ar = 2,6-dimethylphenyl; X = OTf-, BF4-, PF6-, BPh4-) and [(η6-C6H6)Ru(ArN:CMeCHCMe:NAr)][BArF4] [5 ...
