Convenient synthesis of alkylhydrazides by the cobalt-catalyzed hydrohydrazination reaction of olefins and azodicarboxylates

Jérôme Waser
2004
Article

Résumé

Treatment of olefins with an excess of di-tert-Bu azodicarboxylate, an equimolar amt. of PhSiH3, and a catalytic amt. of a Co(III) catalyst afforded the Markovnikov hydrazide products, e.g., I, for a broad range of olefins, in good yields. [on SciFinder (R)]

Source officielle

https://infoscience.epfl.ch/record/114960?ln=fr

À propos de ce résultat

Cette page est générée automatiquement et peut contenir des informations qui ne sont pas correctes, complètes, à jour ou pertinentes par rapport à votre recherche. Il en va de même pour toutes les autres pages de ce site. Veillez à vérifier les informations auprès des sources officielles de l'EPFL.

Convenient synthesis of alkylhydrazides by the cobalt-catalyzed hydrohydrazination reaction of olefins and azodicarboxylates

Chiral Bronsted Acid-Catalyzed Enantioselective Three-Component Povarov Reaction

The Diels-Alder route to trifluoromethyl-substituted carbo- and heterocycles

Regioselective formation of fluorohydrins and their stereoselective conversion to fluoroolefins

Regioselective formation of fluorohydrins and their stereoselective conversion to fluoroolefins

The Diels-Alder route to trifluoromethyl-substituted carbo- and heterocycles

Chiral Bronsted Acid-Catalyzed Enantioselective Three-Component Povarov Reaction