Publication
Interaction of rabbit secretory component with rabbit IgA dimer
Publications associées (33)
Quantum chemical studies of reactive species in water
In this thesis, quantum chemical methods have been applied to elucidate the thermodynamics and the kinetics of reactions involving reactive species in water. Due to their high reactivity in water, many transient species are difficult to study by experiment ...
EPFL2016Ligand-Protein Affinity Studies Using Long-Lived States of Fluorine-19 Nuclei
Geoffrey Bodenhausen, Daniele Mammoli, Roberto Buratto, Estel Canet Martinez
The lifetimes T-LLS of long-lived states or T-LLC of long-lived coherences can be used for the accurate determination of dissociation constants of weak protein ligand complexes. The remarkable contrast between signals derived from LLS or LLC in free and bo ...
American Chemical Society2016Kinetic and Mechanistic Aspects of the Reactions of Iodide and Hypoiodous Acid with Permanganate: Oxidation and Disproportionation
Oxidation kinetics of iodide and HOI/OI- by permanganate were studied in the pH range of 5.0-10.0. Iodide oxidation and iodate formation were faster at lower pH. The apparent second-order rate constants (k(obs)) for iodide oxidation by permanganate decreas ...
American Chemical Society2016First principles computational chemistry predictions of equilibrium and kinetic constants for electrophilic reactions in water
Jeremy Samuel Arey, Peter Rudolf Tentscher, Daniela Trogolo
Aqueous electrophilic reactions are broadly important in environmental chemistry, but the thermodynamic equilibrium constants, rate constants, and mechanisms describing these reactions are often difficult to determine by experiment. Here we report on our e ...
2015A Pyridine-Based Ligand with Two Hydrazine Functions for Lanthanide Chelation: Remarkable Kinetic Inertness for a Linear, Bishydrated Complex
To study the influence of hydrazine functions in the ligand skeleton, we designed the heptadentate HYD ligand (2,2',2 '',2 ''-(2,2'-(pyridine-2,6-diyl)bis(2-methylhydrazine-2,1,1-triyl)) tetraacetic acid) and compared the thermodynamic, kinetic, and relaxa ...
American Chemical Society2015Fine-particle water and pH in the southeastern United States
Particle water and pH are predicted using meteorological observations (relative humidity (RH), temperature (T)), gas/particle composition, and thermodynamic modeling (ISORROPIA-II). A comprehensive uncertainty analysis is included, and the model is validat ...
Copernicus GmbH2015A critical evaluation of proxy methods used to estimate the acidity of atmospheric particles
Given significant challenges with available measurements of aerosol acidity, proxy methods are frequently used to estimate the acidity of atmospheric particles. In this study, four of the most common aerosol acidity proxies are evaluated and compared: (1) ...
Copernicus GmbH2015Serum Albumin Targeted, pH-Dependent Magnetic Resonance Relaxation Agents
The objective of this work was the synthesis of serum albumin targeted, GdIII-based magnetic resonance imaging (MRI) contrast agents exhibiting a strong pH-dependent relaxivity. Two new complexes (Gd-glu and Gd-bbu) were synthesized based on the DO3A macro ...
2012