Linear Polynuclear Helicates as a Link between Discrete Supramolecular Complexes and Programmed Infinite Polymetallic Chains
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This paper reports a novel topotactic exchange reaction of the ethylenediammonium intercalated mixed-valent vanadyl phosphate, (H3NCH2CH2NH3)0.5[V4+0.45V5+0.55O2PO4{P(OH)2}0.483], with monovalent cations at room temperature. Alkali metal ions and other mon ...
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