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This dissertation addresses the development of a Solid Freeform Fabrication process, Selective Laser Pyrolysis, to fabricate three-dimensional porous ceramic preforms from ceramic powders and preceramic polymers. It contributes to a better understanding of ...
Chemical inertness and corrosion resistance make ceramic materials appropriate for Micro Electro-Mechanical Systems (MEMS) when aiming for sensing applications at high temperature or in harsh environment. Besides the usual fabrication techniques, such as p ...
The effect of the bulk microstructure (grain size distribution, grain boundary composition on the oxygen transport properties of La0.5Sr0.5FeO3membranes was investigated. For this purpose, samples with different microstruct ...
The Derjaguin approximation states that the interaction force between two curved surfaces is proportional to their effective radius, whereby the inverse effective radius is the arithmetic mean of the inverse curvature radii of the surfaces involved. The pr ...
Nanocrystalline metals have been an area of great interest in recent years due to their enhanced characteristics. One of the most striking is implied by the Hall-Petch relation: with decreasing grain size the material becomes stronger. This promise is fulf ...
A combined experimental/simulation approach has been used to characterize the underlying deformation mechanisms associated with stress-assisted grain growth in nanocrystalline Al. Strain rate sensitivity experiments on freestanding submicron thin films und ...
Isothermal NaCl sintering experiments are conducted between 500 and 790 degrees C on powders 75, 100, 150 and 400 mu m in average diameter. Along with literature data, the results are compared with theoretical predictions for the initial stage of sintering ...
Effective interstitial transport of particles is necessary for injected drug/diagnostic agents to reach the intended target; however, quantitative methods to estimate such transport parameters are lacking. In this study we develop an in vivo model for eval ...
This study investigates the composition of free surfaces of neodymium-doped yttrium–aluminum–garnet, using energy minimization techniques. Atomistic modeling shows that the dopant is concentrated in a zone within 0.5 nm ̊of the surface, the enrichment fact ...
The present study reports on the preparation and structural characterization of dense NaNbO3 ceramics with ultrafine grain size. Nanocrystalline raw powders obtained via microemulsion mediated synthesis were consolidated to green compacts, sinterforged to ...